732290-18-5Relevant academic research and scientific papers
The nucleophilic addition of α-metallated 1,3-dioxanes to planar chiral cationic η3-allylmolybdenum complexes. Synthesis of (2E,5S,6R,7E)-6-methyl-8-phenylocta-2,7-dienoic acid methyl ester, a key component of the Cryptophycins
Cooksey, John,Gunn, Andrew,Kocienski, Philip J.,Kuhl, Alexander,Uppal, Sukhjinder,Christopher, John A.,Bell, Richard
, p. 1719 - 1731 (2007/10/03)
Two adjacent stereogenic centres and a pendant alkene were constructed via nucleophilic addition of a 1,3-dioxan-4-ylcopper(I) reagent to a cationic η3-allylmolybdenum complex as part of a synthesis of (2E,5S,6R,7E)-6-methyl-8-phenylocta-2,7-di
