73274-25-6Relevant academic research and scientific papers
9,12-dibromo-3,3-bis(triphenylphosphine-P)-1,2-dicarba-3-hydrido-3-rhoda- closo-dodecaborane-dichloromethane (1/1)
McEneaney, Patricia A.,Spalding, Trevor R.,Meehan, Paul R.,Ferguson, George
, p. 685 - 687 (1997)
In the title complex, [RhH(C2B9H9Br2)(C18H 15P)2].-CH2Cl2, the rhodacarborane molecule adopts a closed icosahedral RhC2B9-cage geometry with adjacent Rh and C atoms. Principal distances include Rh-P 2.345 (2) and 2.276 (2), Rh-C 2.289 (8) and 2.241 (8), and B-Br 1.974 (9) and 1.980 (9) A.
