9,12-dibromo-3,3-bis(triphenylphosphine-P)-1,2-dicarba-3-hydrido-3-rhoda- closo-dodecaborane-dichloromethane (1/1)

DOI: 10.1107/S0108270197003715

Source and publish data:

Acta Crystallographica, Section C: Crystal Structure Communications p. 685 - 687 (1997)

Update date:2022-08-05

Topics:

Authors:

McEneaney, Patricia A.

Spalding, Trevor R.

Meehan, Paul R.

Ferguson, George

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Article abstract of DOI:10.1107/S0108270197003715

In the title complex, [RhH(C₂B₉H₉Br₂)(C₁₈H ₁₅P)₂].-CH₂Cl₂, the rhodacarborane molecule adopts a closed icosahedral RhC₂B₉-cage geometry with adjacent Rh and C atoms. Principal distances include Rh-P 2.345 (2) and 2.276 (2), Rh-C 2.289 (8) and 2.241 (8), and B-Br 1.974 (9) and 1.980 (9) A.

Full text of DOI:10.1107/S0108270197003715

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