73311-48-5

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 35660-91-4 (E)-1-phenyl-2-buten-1-one 

Downstream Products

• 73311-70-3 1-Phenyl-3-phenylsulfanyl-2-vinyl-hexan-1-one 
• 73311-71-4 (E)-1-Phenyl-5-phenylsulfanyl-oct-2-en-1-one 
• 134273-12-4 (2E)-5-phenyl-2-pentanophenone 
• 103548-16-9 (R)-3-phenyl-1,3-dihydroxypropane 
• 56139-59-4 4-oxo-4-phenyl-butyraldehyde 
• 35660-91-4 (E)-1-phenyl-2-buten-1-one 
• 821775-48-8 (+)-(5R,2E)-5-hydroxy-1,5-diphenyl-2-penten-1-one 
• 77987-28-1 (E)-5,5-Dimethoxy-1-phenyl-pent-2-en-1-one 
• 77987-27-0 (E)-5-Methoxy-5-methyl-1-phenyl-hex-2-en-1-one 
• 77987-24-7 (E)-5-methoxy-1-phenylpent-2-en-1-one 
• 77987-29-2 2-Methoxymethyl-1-phenyl-but-3-en-1-one 

Relevant academic research and scientific papers

Lewis base activation of Lewis acids: Vinylogous aldol additions of silyl dienol ethers to aldehydes

Highly regioselective vinylogous aldol additions of silyl dienol ethers derived from simple α,β-unsaturated ketones are described. The catalyst system of silicon tetrachloride activated by chiral bisphosphoramide (R,R)-1 effectively promotes the addition

AN EFFICIENT SYMTHESIS OF SILYL ENOL ETHERS FROM α,β-UNSATURATED ALDEHYDES AND KETONES

α,β-Unsaturated aldehydes and ketones when reacted with NaBr-Me3SiCl-Et3N in DMF at ambient temperature, yield silyl dienol ethers in high yields.