73341-07-8

Upstream product

• 6738-06-3 phenylethynylmagnesium bromide 
• 141186-06-3 trimethyl(2-phenethyl-1,3-dithian-2-yl)silane 
• 31593-39-2 2-phenethyl-[1,3]dithiane 
• 536-74-3 phenylacetylene 
• 61157-31-1 3-phenylpropionyltrimethylsilane 
• 75085-60-8 1,5-diphenyl-3-trimethylsilyl-1-pentyn-3-ol 
• 74-88-4 methyl iodide 
• 4440-01-1 lithium phenylacetylide 

Downstream Products

• 73341-10-3 Trimethyl-((Z)-3-methylsulfanyl-1-phenethyl-propenyloxy)-silane 
• 72551-30-5 (Z)-1-phenyl-3-(trimethylsiloxy)-3-hexene 
• 29898-25-7 1-phenylhexan-3-one 
• 19969-04-1 1-phenyl-heptan-3-one 
• 223776-72-5 1-phenyl-7-octen-3-one 
• 73341-11-4 Trimethyl-((Z)-1-phenethyl-hexa-1,5-dienyloxy)-silane 
• 90729-70-7 (E)-1,5-diphenyl-4-hexen-3-one 
• 75072-68-3 (E)-1,5-Diphenyl-hex-4-en-3-one 
• 73451-42-0 Trimethyl-((Z)-2-methyl-1-phenethyl-pent-1-enyloxy)-silane 
• 73341-12-5 Trimethyl-((Z)-1-phenethyl-pent-1-enyloxy)-silane 
• 70424-30-5 (Z)-trimethyl((5-phenylpent-2-en-3-yl)oxy)silane 

Relevant academic research and scientific papers

SPECIFIC GENERATION OF LITHIATED 3-TRIMETHYLSILOXY-1,2-PROPADIENE DERIVATIVES FROM 1-(TRIMETHYLSILYL)PROPARGYL ALCOHOLS.

1-(Trimethylsilyl)propargyl alcohols have been prepared by treating acyltrimethylsilanes with magnesium acetylides, and their base-induced reactions involving rearrangement of silyl group have been examined. Treatment of the alcohol with an equimolar amou

BASE-INDUCED REARRANGEMENT OF 1-TRIMETHYLSILYLPROPARGYL ALCOHOL. GENERATION OF LITHIATED TRIMETHYLSILOXYALLENES AND THEIR REACTIONS

Under the effect of butyllithium, 1-trimethylsilylpropagyl alcohol undergoes rearrangement to afford the corresponding trimethylsiloxyallene or its lithiated one, which can be used for the preparation of α,β-unsaturated ketone derivatives.