733736-65-7Relevant academic research and scientific papers
Synthesis and spectroscopic characterization of enantiopure protected trans-4-amino-1-oxyl-2,2,6,6-tetramethyl piperidine-3-carboxylic acid (trans β-TOAC)
Wright, Karen,Castries, Augustin De,Sarciaux, Matthieu,Formaggio, Fernando,Toniolo, Claudio,Toffoletti, Antonio,Wakselman, Michel,Mazaleyrat, Jean-Paul
, p. 5573 - 5576 (2007/10/03)
Enantiomerically pure (3R,4S) and (3S,4R) protected 4-amino-1-oxyl-2,2,6,6- tetramethylpiperidine-3-carboxylic acids were synthesized by reduction of the enamines resulting from the condensation of 3-carboxymethyl-1-oxyl-2,2,6,6- tetramethyl-4-piperidone
4-Amino-1-oxyl-2,2,6,6-tetramethylpiperidine-3-carboxylic acid (β-TOAC), the first spin-labelled, cyclic, chiral β-amino acid resolved in an enantiomerically pure state
Wright, Karen,Crisma, Marco,Toniolo, Claudio,T?r?k, Roland,Péter, Antal,Wakselman, Michel,Mazaleyrat, Jean-Paul
, p. 3381 - 3384 (2007/10/03)
Amination of 3-carboxymethyl-1-oxyl-2,2,6,6-tetramethyl-4-piperidone with (R)-α-methylbenzylamine, NaBH3CN reduction of the resulting enamine and removal of the chiral auxiliary from the separated diastereoisomers, led to enantiomerically pure
