7338-50-3Relevant articles and documents
Thermic conversion of benzene into 6-phenylfulvene with high yield mediated by GaP nanocrystals
Gao, Shanmin,Lu, Jun,Zhao, Yan,Chen, Nan,Xie, Yi
, p. 2880 - 2881 (2002)
With GaP nanocrystals being used in a close reaction system, 6-phenylfulvene is successfully obtained via a high yield thermic conversion from benzene, which provides the possibility of applying nanocrystals to mediate organic reactions.
Kinetics and Mechanism of Pyrrolidine Buffer-Catalyzed Fulvene Formation
Sieverding, Paul,Osterbrink, Johanna,Besson, Claire,K?gerler, Paul
, p. 486 - 494 (2019/01/11)
Rapid synthesis of fulvenes is achieved using pyrrolidinium/pyrrolidine buffers in anhydrous acetonitrile. Time-dependent UV-vis absorption and NMR spectroscopy reveal that the rate and yield of fulvene formation depend strongly on both the presence of acid in the medium and the choice of solvent, and they are negatively affected by water. Kinetic data have been collected for various substrates, and the synthetic benefits of the adjusted reaction conditions are showcased. Enhancements of reaction rates are found in comparison to literature procedures. α-Unsaturated fulvenes that were previously difficult to access can now be obtained in good yields.
Synthesis, characterization and cytotoxic activity on breast cancer cells of new half-titanocene derivatives
Sirignano, Esther,Saturnino, Carmela,Botta, Antonio,Sinicropi, Maria Stefania,Caruso, Anna,Pisano, Assunta,Lappano, Rosamaria,Maggiolini, Marcello,Longo, Pasquale
, p. 3458 - 3462 (2013/06/27)
A series of novel titanocene-complexes has been prepared and evaluated for their growth regulatory effects in MCF7 and SkBr3 breast cancer cells. The capability of some of these compound to elicit relevant repressive effects on cancer cell growth could be taken into account towards novel pharmacological approaches in cancer therapy.
