73451-64-6

Basic information

• Product Name: [Dimethyl-(1-trimethylsilanyl-vinyl)-silanyloxymethyl]-benzene
• CAS NO: 73451-64-6
• Molecular Weight: 264.515
• Mol File: 73451-64-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Dimethyl-(1-trimethylsilanyl-vinyl)-silanyloxymethyl]-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [Dimethyl-(1-trimethylsilanyl-vinyl)-silanyloxymethyl]-benzene(73451-64-6)
• EPA Substance Registry System: [Dimethyl-(1-trimethylsilanyl-vinyl)-silanyloxymethyl]-benzene(73451-64-6)

Safety Data

• Hazardous Substances Data: 73451-64-6(Hazardous Substances Data)

Upstream product

• 5926-35-2 chlorobis(trimethylsilyl)methane 
• 2117-28-4 bis(trimethylsilyl)methane 
• 30006-66-7 bis(trimethylsilyl)diazomethane 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Bis(trimethylsilyl)-, Trimethylsilyltrimethylgermyl-, and Bis(trimethylgermyl)diazomethane. Synthesis and Chemistry of Quantitative Silene and Germene Precursors

Convenient syntheses of bis(trimethylsilyl)diazomethane (1), trimethylsilyltrimethylgermyldiazomethane (22), and bis(trimethylgermyl)diazomethane (31), utilizing diazo transfer from tosyl azide to the carbanion derived from the corresponding bis(trimethylmetallo)methane or -chloromethane, are described.Both photolysis and thermolysis of 1 produce a carbene which rearranges via methyl migration to silene 3, which dimerizes.Trapping results with methanol, benzaldehyde, 1,3-butadiene, 2,3-dimethyl-1,3-butadiene, and D2O indicate that silene formation is essentially quantitative.Thermolysis of 23 produces only products from silene intermediacy, but photolysis and trapping with MeOD reveal a competition between silene and germene formation which favors the silene by a factor of 4.Both photolysis and pyrolysis of 31 produce only products from the germene resulting from methyl migration to carbon.