7348-54-1Relevant academic research and scientific papers
DISPROPORTIONATION OF HYDROGEN IN 3-CARENE
Manukov, E. N.,Chuiko, V. A.,Vyglazov, O. G.
, p. 257 - 262 (2007/10/02)
The disproportionation of hydrogen in 3-carene takes place with the formation of compounds of the 1,1,4-trimethylcycloheptane series.The proposed reaction mechanism involves dehydration of the 2-carene to 2,4-caradiene, which exists in a rapid tautomeric equilibrium with 3,7,7-trimethyl-1,3,5-cycloheptatriene.This gives rise to the appearance of compounds with a seven-membered ring in the reaction product.
HETEROGENEOUS HYDROGENATION OF 3,7,7-TRIMETHYLCYCLOHEPTA-1,3,5-TRIENE
Manukov, E. N.,Chuiko, V. A.
, p. 422 - 425 (2007/10/02)
It has been shown that the intermediate products of the hydrogenation of 3,7,7-trimethylcyclohepta-1,3,5-triene on platinum black are 2- and 3-carenes, in addition to olefins and dienes of the 1,1,4-trimethylcycloheptane series.The final hydrogenation products contains 96percent of 1,1,4-trimethylcycloheptane and 4percent of carenes.
