735-69-3Relevant academic research and scientific papers
Reactions of 2-Aryl(Alkyl)-4,6-bis(alkylthio)-1,3,5-oxadiazinium Salts with Nucleopiles
Herrmann, Dieter,Lohre, Wolfgang
, p. 1874 - 1881 (2007/10/02)
2-Aryl(Alkyl)-4,6-bis(alkylthio)-1,3,5-oxadiazinium salts 2 react with ammonia and amidines to give the derivatives 6,7, and 8 of 1,3,5-triazine.Reactions of 2 with hydrazine or hydrogen sulfide yield S-methyl N-(5-aryl-4H-1,2,4-triazol-3-yl)thiocarbamidates 5 or S-methyl N-(5-aryl-3H-1,2,4-dithiazol-3-ylidene)thiocarbamidates 9, respectively.
Reactions with N-Acylimino-dithiocarbonic-acid-diesters
Augustin, M.,Richter, M.,Salas, S.
, p. 55 - 68 (2007/10/02)
Reactions of N-acylimino-dithiocarbonic-acid-S,S-diesters 1 with nucleophilic compounds present new possibilities to synthesize heterocycles.With amines 1a reacts by mono- and disubstitution, respectively, of methylthio-groups to isothioureas 2 and guanidines 3, with 1,2-binucleophilic arenes to benzoheterocycles 4, with aliphatic diamines to imidazolines 5, pyrimidines 6, diazepines 7 and the hexamethylene-diamine-derivatives 8. 1a reacts also with hydrazines to 1,2,4-triazoles 9 and with hydrazides to the thiosemicarbazones 10 or 1,3,4-oxadiazoles 11.Heterocyclisations of 1 with guanidines, thiourea, salts of thiourea and amidines give the 1,3,5-triazines 12, 14, 15 and 16.N-benzoyl-dithiocarbonic-acid-methylester -amid reacts with CH-acidic compounds to thiazoles 17.The structures of the final products are determined by i.r.-, 1H-n.m.r.-, u.v.- and mass-spectras.
