73501-69-6Relevant academic research and scientific papers
Electrophilic azido selenenylation of alkenes. A simple synthetic route to racemic taxol side chain
Tiecco, Marcello,Testaferri, Lorenzo,Temperini, Andrea,Bagnoli, Luana,Marini, Francesca,Santi, Claudio
, p. 2167 - 2179 (2007/10/03)
Simple alkenes react with PhSeOTf and NaN3 in MeCN to afford β- phenylseleno azides as the result of a stereospecific trans addition. The regioselectivity of the process is determined by the structure of the alkene.
Pyrrolidines from olefins via radical cyclization
Gupta, Vijay,Besev, Magnus,Engman, Lars
, p. 2429 - 2432 (2007/10/03)
2,4-Disubstituted N-tosylpyrrolidines were prepared from olifeins via N- tosylaziridination, benseneselenolate ring-opening and reductive radical cyclization. Azidoselenation of olefins, followed by reduction, N-tosylation, N-allylation and reductive radical cyclization, afforded 3,4-disubstituted N- tosylpyrrolidines.
Novel Azido-phenylselenenylation of Double Bonds. Evidences for a Free Radical Process
Tingoli, Marco,Tiecco, Marcello,Chianelli, Donatella,Balducci, Roberta,Temperini, Andrea
, p. 6809 - 6813 (2007/10/02)
A simple and mild azido-phenylselenenylation of terminal alkenes, which proceeds with complete anti-Markovnikov regioselectivity, has been developed.This reaction occurs when the alkenes are treated with (diacetoxyiodo)benzene, sodium azide, and diphenyl
