73502-42-8Relevant articles and documents
Trimethylsilyl enyne complex and method of synthesis thereof
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Paragraph 0026; 0027; 0028; 0029; 0030; 0031, (2017/09/01)
The invention relates to a trimethylsilyl enyne complex, the chemical structure of the complex is related in the application. Substituent group R1 is shorten as phenyl or methyl phenyl or n-octyl or a random sort of cyclohexyl, substituent group R2 is sho
A convenient method for the aromatic amino-claisen rearrangement of N-(1,1-disubstituted-allyl)anilines
Cooper,Lucas,Taylor,Ward,Williamson
, p. 621 - 625 (2007/10/03)
N-(1,1-Disubstituted-allyl)anilines are rearranged cleanly and in high yield to 2-(3,3-disubstituted-allyl)anilines using a catalytic amount of p-toluenesulfonic acid in acetonitrile/water (10:1).
DEHYDRATION OF TERITARY ARYL TRIMETHYLSILYL ACETYLENIC ALCOHOLS
Bychkova, N. A.,Zotchik, N. V.,Rubtsov, I. A.
, p. 1400 - 1404 (2007/10/02)
The dehydration of tertiary aryl acetylenic alcohols with a free and with a protected ethynyl hydrogen was investigated.The introduction of a trimethylsilyl protecting group leads to a considerable acceleration of the dehydration process and a rise in the