73505-25-6Relevant academic research and scientific papers
Facile preparation of bis(thiocarbonyl)disulfides via elimination
Weber, Wolfgang G.,McLeary, James B.,Sanderson, Ron D.
, p. 4771 - 4774 (2006)
A robust facile synthetic preparation of bis(thiocarbonyl)disulfides is presented. The route follows an elimination mechanism rather than the more common oxidation. Addition of p-tosyl chloride to a thiocarbonyl thiolate results in the elimination of the chloride by the trithiocarbonate anion and subsequent elimination of the tosyl leaving group (by a second thiocarbonyl thiolate). The side products of the reaction are bis(4-methylphenyl)disulfone and tosylate salts/acids.
2,2,4,4-Tetrathio substituted 1,3-dithietanes
Weber, Wolfgang,Chirowodza, Helen,Pasch, Harald
, p. 2017 - 2021 (2013/03/14)
The synthesis of 2,2,4,4-tetrathio substituted 1,3-dithietanes and their intermediates by reaction of thiophosgene with carbonotrithioates or O-ethyldithiocarbonate is reported. Their reactivity against thermolysis and aminolysis was investigated.
Redox Reactions in Non-aqueous Media. Determination of Xanthates and Organotrithiocarbonates (Thioxanthates) with Iron(III) in Acetonitrile
Verma, B. C.,Sharma, Neelam,Sud, Anila,Sharma, Usha,Sud, Anita
, p. 625 - 626 (2007/10/02)
The use of iron(III) perchlorate (in acetonitrile) for the visual, potentiometric and spectrophotometric determination of xanthates and organotrithiocarbonates (thioxanthates) in acetonitrile medium is described.The proposed methods are simple, accurate and reliable and show the promise of wide applicability.
Reactions of Toluene-p-sulphonic Thioanhydride with Sulphur Nucleophiles
Hansen, Holger C.,Senning, Alexander
, p. 692 - 693 (2007/10/02)
Ethoxythiocarbonyl p-tolylsulphonyl disulphide (5), benzylthio(thiocarbonyl) p-tolylsulphonyl disulphide (1c), and NN-dimethylthiocarbamoyl p-tolylsulphonyl disulphide (10) are formed in the reactions of toluene-p-sulphonic thioanhydride (3) with O-ethyl dithiocarbonate (4), benzyl trithiocarbonate (2), and NN-dimethyl dithiocarbamate (9) ions, respectively.
