73541-95-4

Basic information

• Product Name: methyl 3,4-anhydro-2-deoxy-6-O-(triphenylmethyl)-α-D-ribo-hexopyranoside
• Synonyms: methyl 3,4-anhydro-2-deoxy-6-O-(triphenylmethyl)-α-D-ribo-hexopyranoside
• CAS NO: 73541-95-4
• Molecular Weight: 402.49
• Mol File: 73541-95-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: methyl 3,4-anhydro-2-deoxy-6-O-(triphenylmethyl)-α-D-ribo-hexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3,4-anhydro-2-deoxy-6-O-(triphenylmethyl)-α-D-ribo-hexopyranoside(73541-95-4)
• EPA Substance Registry System: methyl 3,4-anhydro-2-deoxy-6-O-(triphenylmethyl)-α-D-ribo-hexopyranoside(73541-95-4)

Safety Data

• Hazardous Substances Data: 73541-95-4(Hazardous Substances Data)

Upstream product

• 73541-96-5 (2S,3R,4S,6S)-6-Methoxy-3-methyl-2-trityloxymethyl-tetrahydro-pyran-4-ol 
• 73573-78-1 methyl 2-(acetoxymercurio)-2-deoxy-α-D-mannopyranoside 
• 2873-29-2 D-glucal triacetate 
• 13265-84-4 D-glucal 
• 13145-22-7 methyl 2-deoxy-α-D-glucopyranoside 
• 73573-78-1 C₉H₁₆HgO₇ 
• 102628-74-0 C₇H₁₃ClHgO₅ 
• 73541-94-3 methyl 2-deoxy-6-O-(triphenylmethyl)-α-D-arabinohexopyranoside 

Downstream Products

• 73541-96-5 (2S,3R,4S,6S)-6-Methoxy-3-methyl-2-trityloxymethyl-tetrahydro-pyran-4-ol 
• 86030-92-4 methyl 2,4-dideoxy-6-O-(triphenylmethyl)-α-D-erythro-hexopyranoside 
• 91312-60-6 methyl 2,3-dideoxy-6-O-trityl-α-D-erythro-hexopyranoside 
• 102276-89-1 methyl-2,3-dideoxy-2,3-dehydro-6-O-trityl-α-D-glucopyranoside 
• 103456-59-3 methyl 2,4-dideoxy-3-O-methyl-6-O-trityl-α-D-erythro-hexopyranoside 
• 103438-11-5 (2R,3S,6S)-3,6-Dimethoxy-2-trityloxymethyl-tetrahydro-pyran 
• 103438-12-6 methyl 2,4-dideoxy-3-O-methyl-α-D-erythro-hexopyranoside, p-toluenesulfonate 
• 84751-40-6 methyl (1S,4R,4aS,5R,8S,8aR)-1,3,4,5,8,8a-hexahydro-5-(phenylthio)-8-<2-((2R,4R,6S)-tetrahydro-4,6-dimethoxy-2H-pyran-2-yl)-ethyl>-1,4-epoxynaphthalene-4a(2H)-carboxylate 
• 84800-51-1 (3E)-(2S,4R,6R)-tetrahydro-2,4-dimethoxy-6-<6-(phenylthio)-3,5-hexadienyl>-2H-pyran 
• 103438-17-1 (1R,2R,3R,6S,7R,8S)-3-[2-((2R,4R,6S)-4,6-Dimethoxy-tetrahydro-pyran-2-yl)-ethyl]-6-phenylsulfanyl-11-oxa-tricyclo[6.2.1.0^2,7]undec-4-ene-2-carboxylic acid methyl ester 
• 84751-58-6 (3E)-(2S,4R,6R)-tetrahydro-2,4-dimethoxy-6-<6-(phenylthio)-3,5-hexadienyl>-2H-pyran 
• 84751-58-6 (2S,4R,6R)-2,4-Dimethoxy-6-((3E,5E)-6-phenylsulfanyl-hexa-3,5-dienyl)-tetrahydro-pyran 
• 73573-88-3 mevastatin 
• 102538-26-1 methyl 2,4-dideoxy-(5R)-6-(phenoxythioxomethyl)-α-D-allopyranose 

Relevant articles and documents

Preparation of lactones

7-Substituted lower alkyl hept-6-enoates and 4-hydroxytetrahydropyran-2-ones bearing 6-olefinic substituents (e.g.,) ethyl erythro-3,5-dihydroxy-7-phenyl-hept-6-enoates are prepared by a multi-step process. The process involves 3-protected-lower alkyl 3,5

A Highly Convergent Total Synthesis of (+)-Compactin

An intramolecular Diels-Alder approach to the construction of (+)-compactin is described.Alkylation of the lithium enolate of (acetylmethylene)triphenylphosphorane with the tosylate of allenic alcohol 15 affords phosphorane 16, which condenses with aldehyde 6 (prepared from tri-O-acetyl-D-glucal) to afford enone 3.Intramolecular Diels-Alder reaction, reduction with lithium tri-sec-butylborohydride, and acylation with (S)-(+)-2-methylbutyric anhydride yields a chromatographically separable mixture of diastereomers; conversion to compactin was accomplished by acid hydrolysis followed by oxidation.

Synthetic and biological studies of compactin and related compounds. 2 Synthesis of the lactone moiety of compactin

-