73563-15-2Relevant academic research and scientific papers
Mechanistic studies on the electrochemical fluorination of trialkylamines and tetraalkylammonium salts
Dimitrov,Pfeifer,Jonethal,Ruediger,Seppelt
, p. 143 - 150 (2007/10/03)
The comparative electrochemical fluorination (ECF) of selected trialkylamines and tetraalkylammonium salts was studied in order to obtain experimental data allowing a precise valuation of the ECF mechanism. The results of the investigation favour the ECF mechanism already proposed by Simons, via oxidation of F- .(HF)n to F and nHF, as probably the only relevant electrochemical process at the anode. For the first time some experimental proof has been obtained that a direct electrochemical oxidation of the substrate can be ruled out as a decisive step in ECF.
HEXA-, HEPTA- UND OCTAFLUORTRIMETHYLAMIN
Buerger, H.,Niepel, H.,Pawelke, G.,Frohn, H. J.,Sartori, P.
, p. 231 - 238 (2007/10/02)
The electrofluorination of N(CH3)3 yields, along with fragmentation and recombination products and N(CF3)3 (I), minor quantities of the hitherto unknown compounds (CF3)2NCF2H (II), CF3N(CF2H)2 (III) and N(CF2H)3 (IV).I-IV have been isolated and characterized by their (1)H, (13)C and (19)F nmr and their EI and CI mass spectra.
