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Trimethylamine in stock
Cas No: 75-50-3
USD $ 3.0-3.0 / Kilogram 1 Kilogram 100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality Trimethylamine Hydrochloride supplier in China
Cas No: 75-50-3
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Trimethylamine
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Trimethylamine aqueous solution 30%
Cas No: 75-50-3
USD $ 2.0-3.0 / Kilogram 1 Kilogram 50 Metric Ton/Day EAST CHEMSOURCES LIMITED Contact Supplier
Amadis Chemical offer CAS#75-50-3;CAT#A838436
Cas No: 75-50-3
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Trimethylamine
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TIANFU-CHEM CAS:75-50-3 TRIMETHYLAMINE HYDROCHLORIDE
Cas No: 75-50-3
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Trimethylamine Amino compounds
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USD $ 70.0-90.0 / Kilogram 1 Kilogram 100 Kilogram/Week Baoji Guokang Healthchem co.,ltd Contact Supplier
Nice Quality Trimethylamine Cas No: 75-50-3
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USD $ 1.0-3.0 / Gram 10 Gram 1000 Kilogram/Month Wuhan Monad Medicine Tech Co.,LTD Contact Supplier
Manufacturer Supply Top quality Trimethylamine solution
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75-50-3 Usage

Air & Water Reactions

Highly flammable and easily ignited. Water soluble.

Fire Hazard

FLAMMABLE. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Vapor is heavier than air and may travel a considerable distance to a source of ignition and flash back.

Reactivity Profile

TRIMETHYLAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. Contamination of an ethylene oxide tank with trimethylamine caused an explosion [BCISC Quart. Safety Summ., 1966, 37, 44].

Purification Methods

Dry triethylamine by passing the gas through a tower filled with solid KOH. Water and impurities containing labile hydrogen were removed by treatment with freshly sublimed, ground, P2O5. It has been refluxed with acetic anhydride, and then distilled through a tube packed with HgO and BaO. [Comyns J Chem Soc 1557 1955.] For more extensive purification, trimethylamine is converted to the hydrochloride, crystallised (see below), and regenerated by treating the hydrochloride with excess aqueous 50% KOH, the gas is passed through a CaSO4 column into a steel cylinder containing sodium ribbon. After 1-2 days, the cylinder is cooled to -78o and hydrogen and air are removed by pumping. [Day & Felsing J Am Chem Soc 72 1698 1950.] Me3N has been distlled from trap-to-trap and degassed by freeze-pump-thaw [Halpern et al. J Am Chem Soc 108 3907 1986]. It is commercially supplied in a pressure tin. [Beilstein 4 H 43, 4 I 322, 4 II 553, 4 III 99, 4 IV 134.]

Uses

Organic synthesis, especially of choline salts, warning agent for natural gas, manufacture of disinfectants, flotation agent, insect attractant, quaternary ammonium compounds, plastics.

Chemical Properties

Colorless gas at room temperature; fishy ammoniacal odor; readily liquefied. Anhydrous form shipped as liquefied compressed gas. Soluble in water, alcohol, and ether.

Definition

ChEBI: A tertiary amine that is ammonia in which each hydrogen atom is substituted by an methyl group.

Health Hazard

VAPOR: POISONOUS IF INHALED. Irritating to eyes, nose, and throat. LIQUID: Will burn skin and eyes. Harmful if swallowed.

General Description

A colorless gas with a fishlike odor at low concentrations changing to ammonia-like odor at higher concentrations. Shipped as a liquid under its own vapor pressure. Contact with the unconfined liquid can cause frostbite from evaporative cooling or chemical type burns. The gasis corrosive and dissolves in water to form flammable, corrosive solutions. Gas is an asphyxiate by the displacement of air. Produces toxic oxides of nitrogen during combustion. Prolonged exposure to heat can cause the containers to rupture violently and rocket. Long-term inhalation of low concentrations or short -term inhalation of high concentrations has adverse health effects.
InChI:InChI=1S/C3H9N/c1-4(2)3/h1-3H3

75-50-3 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (43282)  Trimethylamine, 45% w/w aq. soln.    75-50-3 2.5L 2014.0CNY Detail
Alfa Aesar (43282)  Trimethylamine, 45% w/w aq. soln.    75-50-3 500ml 403.0CNY Detail
Alfa Aesar (H27324)  Trimethylamine, 33% w/w in ethanol    75-50-3 1000ml 1230.0CNY Detail
Alfa Aesar (H27324)  Trimethylamine, 33% w/w in ethanol    75-50-3 250ml 366.0CNY Detail
Alfa Aesar (H32899)  Trimethylamine, 1M soln. in THF    75-50-3 500ml 1654.0CNY Detail
Alfa Aesar (H32899)  Trimethylamine, 1M soln. in THF    75-50-3 100ml 651.0CNY Detail
TCI America (T3567)  Trimethylamine (ca. 13% in Acetonitrile, ca. 2mol/L)   75-50-3 500mL 890.00CNY Detail
TCI America (T3567)  Trimethylamine (ca. 13% in Acetonitrile, ca. 2mol/L)   75-50-3 100mL 240.00CNY Detail
TCI America (T2893)  Trimethylamine (ca. 25% in Isopropyl Alcohol, ca. 3mol/L)   75-50-3 500mL 660.00CNY Detail
TCI America (T2893)  Trimethylamine (ca. 25% in Isopropyl Alcohol, ca. 3mol/L)   75-50-3 100mL 210.00CNY Detail
TCI America (T2892)  Trimethylamine (ca. 25% in Ethanol, ca. 3mol/L)   75-50-3 100mL 490.00CNY Detail
TCI America (T2704)  Trimethylamine (ca. 13% in Tetrahydrofuran, ca. 2mol/L)   75-50-3 500mL 640.00CNY Detail

75-50-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name trimethylamine

1.2 Other means of identification

Product number -
Other names TRIMETHYLAMINE HYDRO

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:75-50-3 SDS

75-50-3Synthetic route

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
With Dimethylphenylsilane; C40H56FeN2Si4(2-) In benzene-d6 at 120℃; for 10h; Reagent/catalyst; Sealed tube; Inert atmosphere;99%
With bis(tetrahydrofuran)calcium di(bis(trimethylsilyl)amide); 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane In benzene-d6 at 25℃; for 4h; Inert atmosphere; Schlenk technique; Glovebox;99%
With sodium tetrahydroborate; Bis-(2-bromoethyl)selenium dibromide In tetrahydrofuran at 65℃; for 4h; Product distribution; Mechanism; other temperature (25 deg C), other reaction time, also presence od diethyl selenium dibromide; various other tertiary amides investigated;82%
Dimethylphenylsilane
766-77-8

Dimethylphenylsilane

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
With C40H56N2RuSi4 at 120℃; for 5h; Reagent/catalyst; Sealed tube;99%
With bis(1,5-cyclooctadiene)dichloro[1,3-bis(1′-butylbenzimidazol-2′-yliden-3′-yl)benzene]dirhodium(I) In benzene-d6 at 100℃; for 2h; Catalytic behavior; Time; Reagent/catalyst;89%
carbon dioxide
124-38-9

carbon dioxide

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
With aluminium(III) triflate; [Ru(Triphos)(TMM)]; hydrogen; ammonium chloride In 1,4-dioxane; water at 150℃; under 67506.8 Torr; for 24h; Solvent; Temperature; Pressure; Autoclave; Schlenk technique;99%
With octane; hydrogen; ammonium bicarbonate In neat (no solvent) at 250℃; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Autoclave;65%
With aluminium(III) triflate; [Ru(1,1,1-tris(diphenylphosphinomethyl)ethane)(trimethylenemethane)]; ammonia; hydrogen; bis(trifluoromethanesulfonyl)amide In 1,4-dioxane at 150℃; under 60006 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Time; Inert atmosphere; Autoclave;77 %Spectr.
C17H18ClN3O
85598-30-7

C17H18ClN3O

A

5-(4-chlorophenyl)-3-phenyl-1,2,4-oxadiazole
28825-13-0

5-(4-chlorophenyl)-3-phenyl-1,2,4-oxadiazole

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
at 215℃; for 0.25h;A 98%
B n/a
triethylsilane
617-86-7

triethylsilane

bis-(dimethylamino)methane
51-80-9

bis-(dimethylamino)methane

A

1,1,1-triethyl-N,N-dimethylsilylamine
3550-35-4

1,1,1-triethyl-N,N-dimethylsilylamine

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
With nickel at 140 - 150℃;A 97%
B n/a
C17H19N3O
85598-29-4

C17H19N3O

A

3,5-diphenyl-1,2,4-oxadiazole
888-71-1

3,5-diphenyl-1,2,4-oxadiazole

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
at 210℃; for 0.0833333h;A 97%
B n/a
C18H21N3O
85715-90-8

C18H21N3O

A

3-phenyl-5-(p-tolyl)-1,2,4-oxadiazole
16112-24-6

3-phenyl-5-(p-tolyl)-1,2,4-oxadiazole

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
at 210℃; for 0.166667h;A 97%
B n/a
[(E)-4-(Diethoxy-phosphorylsulfanyl)-but-2-enyl]-trimethyl-ammonium; chloride
108546-39-0

[(E)-4-(Diethoxy-phosphorylsulfanyl)-but-2-enyl]-trimethyl-ammonium; chloride

A

ethyl phosphate
1623-14-9

ethyl phosphate

B

ethyl 1,3-butadienyl sulfide
10574-85-3

ethyl 1,3-butadienyl sulfide

C

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
With potassium hydroxide at 110℃; Product distribution; Mechanism;A 85.4%
B 33.3%
C 96.3%
trimethyl-borane; compound with trimethylamine
856617-42-0

trimethyl-borane; compound with trimethylamine

A

trimethylborane
593-90-8

trimethylborane

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
at 111.3°C, 64.5 Torr equilibrium;A 96%
B 96%
at 111.3°C, 64.5 Torr equilibrium;A 96%
B 96%
at 65.8°C, 47.5 Torr equilibrium;A 63.8%
B 63.8%
propylborane; compound with trimethylamine (1:1)

propylborane; compound with trimethylamine (1:1)

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

A

2-propyl-2,3-dihydro-1H-benzo[1,3,2]diazaborole
115002-30-7

2-propyl-2,3-dihydro-1H-benzo[1,3,2]diazaborole

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
In benzene byproducts: H2; by heating at reflux then cooling, adding pentane to the mixture; recrystn. from benzene-pentane;A 95%
B n/a
isobutylborane; compound with trimethylamine (1:1)

isobutylborane; compound with trimethylamine (1:1)

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

A

2-isobutyl-2,3-dihydro-1H-benzo[1,3,2]diazaborole
114328-55-1

2-isobutyl-2,3-dihydro-1H-benzo[1,3,2]diazaborole

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
In benzene byproducts: H2; reflux, then cooling and adding pentane to the mixture; recrystn. from benzene-pentane;A 95%
B n/a
bis-[(diethoxy-methyl-silanyl)-methyl]-methyl-amine
18551-79-6

bis-[(diethoxy-methyl-silanyl)-methyl]-methyl-amine

phenol
108-95-2

phenol

A

methyltriphenoxysilane
3439-97-2

methyltriphenoxysilane

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
for 1.5h; Heating;A 92%
B n/a
sec-butyl-borane; compound with trimethylamine (1:1)

sec-butyl-borane; compound with trimethylamine (1:1)

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

A

2-sec-butyl-2,3-dihydro-1H-benzo[1,3,2]diazaborole
114328-54-0

2-sec-butyl-2,3-dihydro-1H-benzo[1,3,2]diazaborole

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
In benzene byproducts: H2; by heating at reflux, then cooling and adding pentane to the mixture; recrystn. from benzene-pentane;A 92%
B n/a
trimethylamine-1-benzylborane
124287-34-9

trimethylamine-1-benzylborane

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

A

2-benzyl-2,3-dihydro-1H-benzo[1,3,2]diazaborole
124139-26-0

2-benzyl-2,3-dihydro-1H-benzo[1,3,2]diazaborole

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
In benzene byproducts: H2; reflux, cooling then adding pentane to the mixture; crystn. from benzene-pentane;A 92%
B n/a
potassium sulfite

potassium sulfite

A

potassium dithionate

potassium dithionate

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
With (CH3)3NSO3 In further solvent(s) 12°C, hydrogencarbonatalkal. soln.; cooling the mixture with ice;A 92%
B n/a
With (CH3)3NSO3 In further solvent(s) 12°C, hydrogencarbonatalkal. soln.; cooling the mixture with ice;A 92%
B n/a
isopropylborane; compound with trimethylamine (1:1)

isopropylborane; compound with trimethylamine (1:1)

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

A

2-isopropyl-2,3-dihydro-1H-1,3,2-benzodiazaborole
125929-63-7

2-isopropyl-2,3-dihydro-1H-1,3,2-benzodiazaborole

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
In benzene byproducts: H2; by heating at reflux, then cooling and adding pentane to the mixture; recrystn. from benzene-pentane;A 91%
B n/a
C15H37NO6Si2
382156-73-2

C15H37NO6Si2

phenol
108-95-2

phenol

A

tetraphenoxysilane
1174-72-7

tetraphenoxysilane

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
for 1.5h; Heating;A 89%
B n/a
cyclohexylborane; compound with trimethylamine (1:1)

cyclohexylborane; compound with trimethylamine (1:1)

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

A

2-cyclohexyl-2,3-dihydro-1H-benzo[1,3,2]diazaborole
108484-20-4

2-cyclohexyl-2,3-dihydro-1H-benzo[1,3,2]diazaborole

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
In benzene byproducts: H2; by heating at reflux, cooling and adding pentane to the mixture; recrystn. from benzene-pentane;A 89%
B n/a
acetic acid 15-allyl-3-benzyloxy-13-methyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-17-yl ester
1013940-31-2

acetic acid 15-allyl-3-benzyloxy-13-methyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-17-yl ester

A

acetic acid 3-benzyloxy-15-(3-hydroxy-propyl)-13-methyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-17-yl ester
1013940-33-4

acetic acid 3-benzyloxy-15-(3-hydroxy-propyl)-13-methyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-17-yl ester

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
Stage #1: acetic acid 15-allyl-3-benzyloxy-13-methyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-17-yl ester With 9-bora-bicyclo[3.3.1]nonane In tetrahydrofuran at 10 - 20℃; for 4h;
Stage #2: With trimethylamine-N-oxide In tetrahydrofuran; ethanol; diethylene glycol dimethyl ether at 150℃; for 1h;
A 89%
B n/a
C12H15Cl2N3O
85598-33-0

C12H15Cl2N3O

A

5-(2,4-dichloro-phenyl)-3-methyl-[1,2,4]oxadiazole
59562-67-3

5-(2,4-dichloro-phenyl)-3-methyl-[1,2,4]oxadiazole

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
at 170℃; for 0.5h;A 88%
B n/a
tetrakis(dimethylamido)titanium(IV)

tetrakis(dimethylamido)titanium(IV)

ZrCl4*2N(CH3)3

ZrCl4*2N(CH3)3

A

ZrCl4Ti(N(CH3)2)4
82089-50-7

ZrCl4Ti(N(CH3)2)4

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
In pentane under N2, Ti(NMe2)4 in n-pentane added dropwise to suspn. of ZrCl4*2NMe3 in n-pentane, stirred for 24 h; ppt. collected, washed with n-hexane, dried in vac. for 3 h at room temp.; elem. anal.;A 85.7%
B n/a
bis-[(ethoxy-dimethyl-silanyl)-methyl]-methyl-amine

bis-[(ethoxy-dimethyl-silanyl)-methyl]-methyl-amine

phenol
108-95-2

phenol

A

dimethyl-diphenoxy-silane
3440-02-6

dimethyl-diphenoxy-silane

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
for 1.5h; Heating;A 85%
B n/a
butylborane; compound with trimethylamine (1:1)

butylborane; compound with trimethylamine (1:1)

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

A

2-butyl-2,3-dihydro-1H-benzo[1,3,2]diazaborole
31748-14-8

2-butyl-2,3-dihydro-1H-benzo[1,3,2]diazaborole

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
In benzene byproducts: H2; reflux, then cooling and adding pentane to the mixture; recrystn. from benzene-pentane;A 85%
B n/a
(μ-pyridyl)(μ-hydrido)dirhenium octacarbonyl

(μ-pyridyl)(μ-hydrido)dirhenium octacarbonyl

trimethylamine-N-oxide dihydrate
62637-93-8

trimethylamine-N-oxide dihydrate

A

(μ-hydrido)(μ-pyridyl)(trimethylamine N-oxide)dirhenium heptacarbonyl
84538-00-1

(μ-hydrido)(μ-pyridyl)(trimethylamine N-oxide)dirhenium heptacarbonyl

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
In dichloromethane Re complex dissolved in CH2Cl2, excess Me3NO*2H2O added, stirred vigorously at room temp. for 10 h; filtered, filtrate washed with water, hexane added, slowly evapd.; elem. anal.;A 84%
B n/a
trimethylamine-N-oxide
1184-78-7

trimethylamine-N-oxide

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
With C55H43P3Rh(1+)*C32H12BF24(1-); isopropyl alcohol at 80℃; for 24h; Reagent/catalyst; Inert atmosphere;82%
biochemische Reduktion durch gaerende Zucker-Loesungen;
With zinc
methylammonium 1-methylcaffolide
104815-74-9

methylammonium 1-methylcaffolide

A

3,6,8-trimethyl-1-oxa-3,6,8-triaza-spiro[4.4]nonane-2,4,7,9-tetraone
7366-48-5

3,6,8-trimethyl-1-oxa-3,6,8-triaza-spiro[4.4]nonane-2,4,7,9-tetraone

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
In diethyl ether for 48h;A 80%
B n/a
ammonium caffolide
104795-02-0

ammonium caffolide

A

3,6,8-trimethyl-1-oxa-3,6,8-triaza-spiro[4.4]nonane-2,4,7,9-tetraone
7366-48-5

3,6,8-trimethyl-1-oxa-3,6,8-triaza-spiro[4.4]nonane-2,4,7,9-tetraone

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
In diethyl ether for 48h;A 80%
B n/a
ammonium 1,3-dimethylcaffolide
105116-10-7

ammonium 1,3-dimethylcaffolide

A

3,6,8-trimethyl-1-oxa-3,6,8-triaza-spiro[4.4]nonane-2,4,7,9-tetraone
7366-48-5

3,6,8-trimethyl-1-oxa-3,6,8-triaza-spiro[4.4]nonane-2,4,7,9-tetraone

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
In diethyl ether for 48h;A 80%
B n/a
cis-tetracarbonyl(2-ethoxy-2-oxoethyl)(triphenylphosphine)rhenium

cis-tetracarbonyl(2-ethoxy-2-oxoethyl)(triphenylphosphine)rhenium

trimethylamine-N-oxide
1184-78-7

trimethylamine-N-oxide

fac-(MeCN)(OC)3(Ph3)ReCH2COOEt

fac-(MeCN)(OC)3(Ph3)ReCH2COOEt

B

carbon dioxide
124-38-9

carbon dioxide

C

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
A 80%
B n/a
C n/a
hexylborane; compound with trimethylamine (1:1)

hexylborane; compound with trimethylamine (1:1)

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

A

2-hexyl-2,3-dihydro-1H-benzo[1,3,2]diazaborole
124138-66-5

2-hexyl-2,3-dihydro-1H-benzo[1,3,2]diazaborole

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
In benzene byproducts: H2; reflux, then cooling and adding pentane to the mixture; recrystn. from benzene-pentane;A 79%
B n/a
4-Methylbenzyl bromide
104-81-4

4-Methylbenzyl bromide

trimethylamine
75-50-3

trimethylamine

(4-methylbenzyl)trimethylammonium bromide
16814-21-4

(4-methylbenzyl)trimethylammonium bromide

Conditions
ConditionsYield
In diethyl ether at 0 - 20℃;100%
In tetrahydrofuran; ethanol at 25℃; for 24h; Inert atmosphere;99%
2-chloroethyl methyl ether
627-42-9

2-chloroethyl methyl ether

trimethylamine
75-50-3

trimethylamine

Choline methyl ether chloride
6340-44-9

Choline methyl ether chloride

Conditions
ConditionsYield
In water; acetonitrile at 140℃; for 5.5h;100%
In ethanol at 180℃; for 2.5h;93%
at 95℃;
1,3-propanesultone
1120-71-4

1,3-propanesultone

trimethylamine
75-50-3

trimethylamine

N-(3-sulfonatopropyl)-N,N,N-trimethylammonium
21865-17-8

N-(3-sulfonatopropyl)-N,N,N-trimethylammonium

Conditions
ConditionsYield
In ethanol; acetone at 0 - 20℃; for 24h;100%
In acetone at 35℃; for 2h;86%
In benzene
dichloromethanesulphonyl chloride
41197-29-9

dichloromethanesulphonyl chloride

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

trimethylamine
75-50-3

trimethylamine

A

trichloromethanesulfinyl chloride
25004-95-9

trichloromethanesulfinyl chloride

B

Trimethylammonium-(methylsulfonyl)methansulfonat
14843-83-5

Trimethylammonium-(methylsulfonyl)methansulfonat

Conditions
ConditionsYield
In tetrahydrofuran at -70℃;A 55%
B 100%
Dimethyl phosphite
868-85-9

Dimethyl phosphite

trimethylamine
75-50-3

trimethylamine

tetramethylammonium methyl hydrogen phosphite

tetramethylammonium methyl hydrogen phosphite

Conditions
ConditionsYield
at 20℃; for 24h;100%
dichloromethanesulphonyl chloride
41197-29-9

dichloromethanesulphonyl chloride

trimethylamine
75-50-3

trimethylamine

trimethylammonium trichloromethanesulfinate
98182-00-4

trimethylammonium trichloromethanesulfinate

Conditions
ConditionsYield
In tetrahydrofuran at -70℃;100%
tert-butyl N-[4-(2-bromoethoxy)-3-methoxybenzyl]carbamate
130972-90-6

tert-butyl N-[4-(2-bromoethoxy)-3-methoxybenzyl]carbamate

trimethylamine
75-50-3

trimethylamine

{2-[4-(tert-Butoxycarbonylamino-methyl)-2-methoxy-phenoxy]-ethyl}-trimethyl-ammonium; bromide

{2-[4-(tert-Butoxycarbonylamino-methyl)-2-methoxy-phenoxy]-ethyl}-trimethyl-ammonium; bromide

Conditions
ConditionsYield
In methanol for 18h; Heating;100%
5,10,15,20-tetrakis(4’-bromomethylphenyl)porphyrin

5,10,15,20-tetrakis(4’-bromomethylphenyl)porphyrin

trimethylamine
75-50-3

trimethylamine

5,10,15,20-tetrakis(α-trimethylammonio-4-methylphenyl)phenylporphyrin tetrabromide

5,10,15,20-tetrakis(α-trimethylammonio-4-methylphenyl)phenylporphyrin tetrabromide

Conditions
ConditionsYield
In ethanol at 80℃; for 14h; Substitution;100%
In ethanol; chloroform Reflux;91%
In ethanol at 80℃; for 14h;49%
Toluene-4-sulfonic acid (2R,4R,5R)-5-[1,3]dioxolan-2-yl-4-hydroxy-tetrahydro-furan-2-ylmethyl ester
258336-21-9

Toluene-4-sulfonic acid (2R,4R,5R)-5-[1,3]dioxolan-2-yl-4-hydroxy-tetrahydro-furan-2-ylmethyl ester

trimethylamine
75-50-3

trimethylamine

Toluene-4-sulfonate((2R,4R,5R)-5-[1,3]dioxolan-2-yl-4-hydroxy-tetrahydro-furan-2-ylmethyl)-trimethyl-ammonium;

Toluene-4-sulfonate((2R,4R,5R)-5-[1,3]dioxolan-2-yl-4-hydroxy-tetrahydro-furan-2-ylmethyl)-trimethyl-ammonium;

Conditions
ConditionsYield
In ethanol at 80℃; for 24h; Substitution;100%
C48H36N4O2Ru

C48H36N4O2Ru

trimethylamine
75-50-3

trimethylamine

(meso-Tetrakis{p-tolyl}porphyrinato)bis(trimethylamine)ruthenium(II)

(meso-Tetrakis{p-tolyl}porphyrinato)bis(trimethylamine)ruthenium(II)

Conditions
ConditionsYield
With water for 1h; Reduction;100%
C44H24Cl4N4O2Ru

C44H24Cl4N4O2Ru

trimethylamine
75-50-3

trimethylamine

(meso-Tetrakis{p-chlorophenyl}porphyrinato)bis(trimethylamine)ruthenium(II)

(meso-Tetrakis{p-chlorophenyl}porphyrinato)bis(trimethylamine)ruthenium(II)

Conditions
ConditionsYield
With water for 1h; Reduction;100%
N-tert-Butyloxycarbonyl-L-glutaminyl-L-threonine 2-bromoethyl ester
287178-85-2

N-tert-Butyloxycarbonyl-L-glutaminyl-L-threonine 2-bromoethyl ester

trimethylamine
75-50-3

trimethylamine

N-tert-Butyloxycarbonyl-L-glutaminyl-L-threonine choline ester bromide

N-tert-Butyloxycarbonyl-L-glutaminyl-L-threonine choline ester bromide

Conditions
ConditionsYield
In acetone at 20℃; for 72h; Alkylation;100%
1-bromo-2,4-hexadecadiyne

1-bromo-2,4-hexadecadiyne

trimethylamine
75-50-3

trimethylamine

2,4-hexadecadiynyltrimethylammonium bromide

2,4-hexadecadiynyltrimethylammonium bromide

Conditions
ConditionsYield
In water at 20℃;100%
2-Amino-6-chloropurin
10310-21-1

2-Amino-6-chloropurin

trimethylamine
75-50-3

trimethylamine

2-amino-N,N,N-trimethyl-9H-purine-6-ylammonium chloride
34798-95-3

2-amino-N,N,N-trimethyl-9H-purine-6-ylammonium chloride

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃; for 1h; Inert atmosphere;100%
In ethanol; dimethyl sulfoxide at 20℃; for 12h;76%
In dimethyl sulfoxide for 12h;72%
2-(N-acetylanilino)-4-chloromethyl-1,3-selenazole
62707-38-4

2-(N-acetylanilino)-4-chloromethyl-1,3-selenazole

trimethylamine
75-50-3

trimethylamine

[2-(N-acetylanilino)-1,3-selenazol-4-ylmethyl]trimethylammonium chloride

[2-(N-acetylanilino)-1,3-selenazol-4-ylmethyl]trimethylammonium chloride

Conditions
ConditionsYield
In benzene at 20℃; for 2h;100%
2-(N-acetylanilino)-4-iodomethyl-1,3-selenazole
121995-12-8

2-(N-acetylanilino)-4-iodomethyl-1,3-selenazole

trimethylamine
75-50-3

trimethylamine

[2-(N-acetylanilino)-1,3-selenazol-4-ylmethyl]trimethylammonium iodide

[2-(N-acetylanilino)-1,3-selenazol-4-ylmethyl]trimethylammonium iodide

Conditions
ConditionsYield
In benzene at 20℃; for 2h;100%
1,4-anhydro-2,3-O-isopropylidene-5-O-toluene-p-sulphonyl-DL-ribitol
17118-00-2, 30002-85-8, 84773-09-1

1,4-anhydro-2,3-O-isopropylidene-5-O-toluene-p-sulphonyl-DL-ribitol

trimethylamine
75-50-3

trimethylamine

N-(1,4-anhydro-2,3-O-isopropylidene-D,L-ribitol-5-yl)trimethylammonium tosylate

N-(1,4-anhydro-2,3-O-isopropylidene-D,L-ribitol-5-yl)trimethylammonium tosylate

Conditions
ConditionsYield
In ethanol at 70℃; for 0.25h;100%
4,16-bis(6'-bromohexyl)[2.2]paracyclophane

4,16-bis(6'-bromohexyl)[2.2]paracyclophane

trimethylamine
75-50-3

trimethylamine

4,16-bis(6'-(N,N,N-trimethylammonium)hexyl)[2.2]paracyclophane dibromide

4,16-bis(6'-(N,N,N-trimethylammonium)hexyl)[2.2]paracyclophane dibromide

Conditions
ConditionsYield
In tetrahydrofuran at -78 - 20℃; for 24h;100%
1,4-bis(3',5'-bis(6''-bromohexyl)styryl)benzene
854669-58-2

1,4-bis(3',5'-bis(6''-bromohexyl)styryl)benzene

trimethylamine
75-50-3

trimethylamine

1,4-bis(3',5'-bis(6'-(N,N,N-trimethylammonium)hexyl)styryl)benzene tetrabromide

1,4-bis(3',5'-bis(6'-(N,N,N-trimethylammonium)hexyl)styryl)benzene tetrabromide

Conditions
ConditionsYield
In tetrahydrofuran at -78 - 20℃; for 24h;100%
1,4-bis(4'-(N,N-bis(6''-iodohexyl)amino)styryl)benzene

1,4-bis(4'-(N,N-bis(6''-iodohexyl)amino)styryl)benzene

trimethylamine
75-50-3

trimethylamine

1,4-bis(4'-(N,N-bis(6''-(N,N,N-trimethylammonium)hexyl)amino)styryl)benzene tetraiodide

1,4-bis(4'-(N,N-bis(6''-(N,N,N-trimethylammonium)hexyl)amino)styryl)benzene tetraiodide

Conditions
ConditionsYield
In tetrahydrofuran at -78 - 20℃; for 24h;100%
In tetrahydrofuran; water at -78 - 20℃; for 24h;92%
1-(bromomethyl)-2,5-dichloro-4-methylbenzene
868860-21-3

1-(bromomethyl)-2,5-dichloro-4-methylbenzene

trimethylamine
75-50-3

trimethylamine

2,5-dichloro-(4-methylbenzyl)trimethylammonium bromide

2,5-dichloro-(4-methylbenzyl)trimethylammonium bromide

Conditions
ConditionsYield
In diethyl ether at 0 - 20℃;100%
In diethyl ether at 0 - 20℃;
[14C2-1,4]-1,4-dibromobutane
32330-80-6

[14C2-1,4]-1,4-dibromobutane

trimethylamine
75-50-3

trimethylamine

C8(14)C2H26N2(2+)*2Br(1-)

C8(14)C2H26N2(2+)*2Br(1-)

Conditions
ConditionsYield
In ethanol100%
4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

trimethylamine
75-50-3

trimethylamine

4,4’‐bis(trimethylammoniummethyl)‐2,2’‐bipyridine

4,4’‐bis(trimethylammoniummethyl)‐2,2’‐bipyridine

Conditions
ConditionsYield
In dichloromethane; water at 20℃; for 24h;100%
In ethanol; water at 20℃; for 1h; Inert atmosphere;100%
In ethanol; water at 20℃; for 1h;
In dichloromethane; water at 20℃; for 24h;
In dichloromethane at 20℃; for 24h;
5,15-bis-[4-(3-bromo-propyloxy)-phenyl]-porphyrin

5,15-bis-[4-(3-bromo-propyloxy)-phenyl]-porphyrin

trimethylamine
75-50-3

trimethylamine

5,15-bis-[4-(3-trimethylammonio-propyloxy)-phenyl]-porphyrin dibromide

5,15-bis-[4-(3-trimethylammonio-propyloxy)-phenyl]-porphyrin dibromide

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 50℃; under 750.075 - 1500.15 Torr; for 17h; Autoclave; Industry scale;100%
trimethylaminealane
16842-00-5

trimethylaminealane

trimethylamine
75-50-3

trimethylamine

bis(trimethylamino) alane

bis(trimethylamino) alane

Conditions
ConditionsYield
In not given react. of the Al compd. with an excess of NMe3;100%
6-methylbenzofuran-3-ylmethyl bromide
1187956-06-4

6-methylbenzofuran-3-ylmethyl bromide

trimethylamine
75-50-3

trimethylamine

Br(1-)*C13H18NO(1+)
1187956-09-7

Br(1-)*C13H18NO(1+)

Conditions
ConditionsYield
In tetrahydrofuran; chloroform at 20℃; Inert atmosphere;100%
3-bromomethylbenzofuran
38281-49-1

3-bromomethylbenzofuran

trimethylamine
75-50-3

trimethylamine

Br(1-)*C12H16NO(1+)
1187956-08-6

Br(1-)*C12H16NO(1+)

Conditions
ConditionsYield
In tetrahydrofuran; chloroform at 20℃; Inert atmosphere;100%
Methyl 4-(bromomethyl)benzoate
2417-72-3

Methyl 4-(bromomethyl)benzoate

trimethylamine
75-50-3

trimethylamine

1-(4-(methoxycarbonyl)phenyl)-N,N,N-trimethylmethanammonium bromide
1192363-78-2

1-(4-(methoxycarbonyl)phenyl)-N,N,N-trimethylmethanammonium bromide

Conditions
ConditionsYield
In water; acetonitrile at 80℃; for 15h; Sealed flask;100%
In acetonitrile at 50℃; for 12h;
1-(2,3-dioleyl-5-O-tosyl-α-D-ribofuranosyl)-4-nitroimidazole
1231718-49-2

1-(2,3-dioleyl-5-O-tosyl-α-D-ribofuranosyl)-4-nitroimidazole

trimethylamine
75-50-3

trimethylamine

1-(2,3-dioleyl-5-trimethylammonium-α-D-ribofuranosyl)-4-nitroimidazole tosylate
1231718-52-7

1-(2,3-dioleyl-5-trimethylammonium-α-D-ribofuranosyl)-4-nitroimidazole tosylate

Conditions
ConditionsYield
In tetrahydrofuran; acetonitrile at 50℃; for 48h;100%
1-(2,3-dioleyl-5-O-tosyl-α-D-ribofuranosyl)-5-nitroindole
1231718-39-0

1-(2,3-dioleyl-5-O-tosyl-α-D-ribofuranosyl)-5-nitroindole

trimethylamine
75-50-3

trimethylamine

1-(2,3-dioleyl-5-trimethylammonium-α-D-ribofuranosyl)-5-nitroindole tosylate
1231718-42-5

1-(2,3-dioleyl-5-trimethylammonium-α-D-ribofuranosyl)-5-nitroindole tosylate

Conditions
ConditionsYield
In tetrahydrofuran; acetonitrile at 50℃; for 48h;100%

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