73611-02-6

Basic information

• Product Name: 3-Oxabicyclo[3.1.0]hexan-2-one, 4-hydroxy-6,6-dimethyl-, (1R,4R,5S)-
• CAS NO: 73611-02-6
• Molecular Formula: C7H10O3
• Molecular Weight: 142.155
• Mol File: 73611-02-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-Oxabicyclo[3.1.0]hexan-2-one, 4-hydroxy-6,6-dimethyl-, (1R,4R,5S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Oxabicyclo[3.1.0]hexan-2-one, 4-hydroxy-6,6-dimethyl-, (1R,4R,5S)-(73611-02-6)
• EPA Substance Registry System: 3-Oxabicyclo[3.1.0]hexan-2-one, 4-hydroxy-6,6-dimethyl-, (1R,4R,5S)-(73611-02-6)

Safety Data

• Hazardous Substances Data: 73611-02-6(Hazardous Substances Data)

Upstream product

• 474429-71-5 C₉H₁₂O₅ 
• 67-56-1 methanol 
• 1381843-47-5 C₂₂H₂₄O₇ 
• 1381843-39-5 C₂₂H₂₄O₇ 
• 1381843-06-6 C₂₁H₃₄O₆Si 

Downstream Products

• 1381843-18-0 C₂₂H₂₄O₇ 
• 1381843-39-5 C₂₂H₂₄O₇ 
• 1381843-47-5 C₂₂H₂₄O₇ 
• 76740-09-5 (1R,5S) 6,6-dimethyl-4(R)-[(1'S), (2'R), (5'S) 2'-isopropyl-5'-methyl-cyclohexanoxy]-3-oxabicyclo-(3,1,0)-hexan-2-one 
• 84368-72-9 (1S,3R)-2,2-Dimethyl-3-vinyl-cyclopropanecarbonyl chloride 

Relevant articles and documents

Efficient resolution of some monoprotected derivatives of Corey lactone

Racemic monoprotected at primary hydroxy group Corey lactones were resolved using (1S,2R,5R)-6,6-dimethyl-4-oxo-3-oxabicyclo-[3.1.0]hexan-2-ol as a chiral auxiliary reagent of hemiacylal chemotype.

A SYNTHESIS OF TRANS- AND CIS-CARONALDEHYDES

A preparation of trans- and cis-caronaldehyde derivatives is described by employing iodolactonization reaction as a key step.Investigation is also carried out to establish an asymmetric synthesis by employing the same methodology which allows diastereoselective formation of optically active intermediates in both enantiomeric forms from a single precursor though the degree of asymmetric induction is found to be less satisfactory.