73653-01-7Relevant academic research and scientific papers
Efficient heterogeneous oxidation of alkylarenes with molecular oxygen
Kamata, Keigo,Kasai, Jun,Yamaguchi, Kazuya,Mizuno, Noritaka
, p. 3577 - 3580 (2007/10/03)
(Chemical Equation Presented) Ru(OH)x/Al2O 3 efficiently catalyzes the heterogeneous aerobic oxygenation or oxidative dehydrogenation of alkylarenes to give the corresponding oxygenated or dehydrogenated products. Catalyst/product separation is very easy, and the recovered catalyst is reusable with retention of the high catalytic performance.
Stereoelectronic effects in the deprotonation of arylalkyl radical cations: meso-ethylanthracenes
Tolbert, Laren M.,Khanna, Rajive K.,Popp, Ann E.,Gelbaum, Leslie,Bottomley, Lawrence A.
, p. 2373 - 2378 (2007/10/02)
In contrast to meso-methylanthracenes, which are oxidized by one-electron oxidants to hydroxymethyl derivatives, meso-ethylanthracenes such as 9,10-diethylanthracene (DEA) undergo a facile chemical or biochemical oxidative elimination of ethylene to yield an anthrone. No trace of ethyl side chain oxidation to a 1-hydroxyethyl derivative is observed. The rationale for this dramatic selection between methyl and ethyl reactivity is a stereoelectronic effect on radical cation deprotonation. 9-Ethyl-10-methylanthracene (EMA) undergoes both oxidative pathways, but the competition between the two pathways is mediated by water. This effect is attributed to the intervention of a water cluster in the deprotonation reaction.
