10-Methylanthracen-9(10H)-one

Base Information

• Chemical Name: 10-Methylanthracen-9(10H)-one
• CAS No.: 73653-01-7
• Molecular Formula: C15H12O
• Molecular Weight: 208.26
• DSSTox Substance ID: DTXSID50506002
• Nikkaji Number: J439.614F
• Wikidata: Q82361524
• Mol file: 73653-01-7.mol

Synonyms:10-Methylanthracen-9(10H)-one;9-Methylanthron;73653-01-7;10-METHYL-10H-ANTHRACEN-9-ONE;SCHEMBL6901219;DTXSID50506002;10-Methyl-9(10H)-anthracenone;YKGYKLOGMNMPOC-UHFFFAOYSA-N;AKOS000281093

Chemical Property of 10-Methylanthracen-9(10H)-one

Chemical Property:

• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 208.088815002
• Heavy Atom Count: 16
• Complexity: 257

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1C2=CC=CC=C2C(=O)C3=CC=CC=C13

Technology Process of 10-Methylanthracen-9(10H)-one

There total 4 articles about 10-Methylanthracen-9(10H)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

9,10-dihydro-9-methylanthracene (17239-99-5) → 9-methylanthracene (779-02-2) + 10-methylanthrone (73653-01-7)

Guidance literature:

With aluminum oxide; Ru(OH)_x; oxygen; In 1,2-dichloro-benzene; at 169.85 ℃; for 1.5h; under 760 Torr;

DOI:10.1021/ol0485363

Reference yield:

9-ethyl-10-methylanthracene (19713-49-6) → ethanol (64-17-5) + ethene (74-85-1) + 9-ethyl-10-(hydroxymethyl)anthracene (29852-41-3) + 10-methylanthrone (73653-01-7) + 9-ethyl-10-anthracenecarboxaldehyde (108617-90-9)

Guidance literature:

With tris(1,10-phenanthroline)iron(III) tris(hexafluorophosphate); water; In acetonitrile; at 25 ℃; for 0.5h; Product distribution; Rate constant; k_H/k_D for the formation of anthrone; other oxidant and times; var. anthracenes;

DOI:10.1021/ja00162a043

Reference yield:

9-ethyl-10-methylanthracene radical cation → ethanol (64-17-5) + ethene (74-85-1) + 9-ethyl-10-(hydroxymethyl)anthracene (29852-41-3) + 10-methylanthrone (73653-01-7) + 9-ethyl-10-anthracenecarboxaldehyde (108617-90-9)

Guidance literature:

With tris(1,10-phenanthroline)iron(III) tris(hexafluorophosphate); water; In acetonitrile; at 25 ℃; for 0.5h; Rate constant; Mechanism; Product distribution;

DOI:10.1021/ja00162a043

upstream raw materials:

9-ethyl-10-methylanthracene

9,10-dihydro-9-methylanthracene

Downstream raw materials:

1-(10-Benzoyloxy-<9>anthryl)-2-(10-oxo-9,10-dihydro-<9>anthryl)-ethan

9-bromomethyl-10-phenyl-anthracene

9,10-dibromomethylanthracene

9-methylanthracene

Refernces

• 1、 Tolbert, Laren M.,Khanna, Rajive K.,Popp, Ann E.,Gelbaum, Leslie,Bottomley, Lawrence A.. "Stereoelectronic effects in the deprotonation of arylalkyl radical cations: meso-ethylanthracenes". . p. 2373 - 2378. Retrieved 2007/10/02.