73664-46-7

Basic information

• Product Name: N,N-Bis(2-pyridinyl)acetamide
• Synonyms: N,N-Bis(2-pyridinyl)acetamide;N,N-Di(2-pyridinyl)acetamide;N,N-Di(2-pyridyl)acetamide
• CAS NO: 73664-46-7
• Molecular Formula: C12H11N3O
• Molecular Weight: 213.2352
• Mol File: 73664-46-7.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 472°Cat760mmHg
• Flash Point: 239.3°C
• Appearance: /
• Density: 1.224g/cm³
• Vapor Pressure: 4.43E-09mmHg at 25°C
• Refractive Index: 1.62
• CAS DataBase Reference: N,N-Bis(2-pyridinyl)acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-Bis(2-pyridinyl)acetamide(73664-46-7)
• EPA Substance Registry System: N,N-Bis(2-pyridinyl)acetamide(73664-46-7)

Safety Data

• Hazardous Substances Data: 73664-46-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H11N3O/c1-10(16)15(11-6-2-4-8-13-11)12-7-3-5-9-14-12/h2-9H,1H3

Upstream product

• 1202-34-2 di(pyridin-2-yl)amine 
• 75-36-5 acetyl chloride 

Relevant articles and documents

N-Acetyl-N,N-dipyrid-2-yl (cyclooctadiene) rhodium (I) and iridium (I) complexes: Synthesis, X-ray structures, their use in hydroformylation and carbonyl hydrosilylation reactions and in the polymerization of diazocompounds

The synthesis of novel N-acetyl-N,N-dipyrid-2-yl complexes of RhI and IrI, i.e. [RhCl(CH3CONPy2)(COD)] (1) and [IrCl(CH3CONPy2)(COD)] (2), respectively, is described. Upon prolonged treatment in CH2Cl2 at room temperature, complex 1 is transformed into a cationic Rh-complex, i.e. [Rh(CH3CONPy2)(COD)+RhCl2(COD)-] (1a). Compound 1a crystallizes in the monoclinic space group P21/c, complex 2 crystallizes in the triclinic space group P over(1, ?). Compound 1 was investigated for its catalytic activity in the hydroformylation of cyclooctene as well as of 1-octene. In addition, 1 was used in various carbonyl hydrosilylation reactions of both aldehydes and ketones. There, turn-over numbers up to 50 000 and yields in the range of 85-100% were observed. Finally, compound 1 was successfully used for the polymerization of N2CHCOOEt yielding highly stereoregular poly(ethoxycarbonylcarbene) with Mw = 67 000 g/mol and a polydispersity index (PDI) of 2.59.