7367-83-1

Basic information

• Product Name: METHYL-CIS-4-DECENOATE
• Synonyms: METHYL-CIS-4-DECENOATE;methyl (Z)-4-decenoate;4-Decenoic acid, methyl ester, (4Z)-;METHYLDEC-4-ENOATE;(Z)-4-Decenoic acid methyl ester
• CAS NO: 7367-83-1
• Molecular Formula: C₁₁H₂₀O₂
• Molecular Weight: 184.28
• EINECS: 230-914-7
• Mol File: 7367-83-1.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 216.8 °C at 760 mmHg
• Flash Point: 68.9 °C
• Appearance: /
• Density: 0.889 g/cm³
• Vapor Pressure: 0.138mmHg at 25°C
• Refractive Index: 1.442
• CAS DataBase Reference: METHYL-CIS-4-DECENOATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL-CIS-4-DECENOATE(7367-83-1)
• EPA Substance Registry System: METHYL-CIS-4-DECENOATE(7367-83-1)

Safety Data

• Hazardous Substances Data: 7367-83-1(Hazardous Substances Data)

Usage

General Description

Methyl-cis-4-decenoate is a chemical compound that belongs to the family of esters. It is commonly used in the fragrance and flavor industry as a scent ingredient, providing a fruity and floral aroma with citrus and green undertones. METHYL-CIS-4-DECENOATE is widely utilized in the production of perfumes, colognes, and scented products, as well as in food and beverage flavorings. Additionally, it can also be employed in the manufacturing of soaps, lotions, and other personal care products due to its pleasant fragrance. Methyl-cis-4-decenoate is typically derived from natural sources such as fruits and flowers, and it is known for its high stability and low volatility, making it a popular choice in the formulation of long-lasting and impactful aromas.

InChI:InChI=1/C11H20O2/c1-3-4-5-6-7-8-9-10-11(12)13-2/h7-8H,3-6,9-10H2,1-2H3/b8-7-

Upstream product

• 186581-53-3 diazomethane 
• 505-90-8 (Z)-dec-4-enoic acid 
• 30390-50-2 (Z)-4-decenal 
• 13395-34-1 (3-(methoxycarbonyl)propyl)triphenylphosphonium bromide 
• 66-25-1 hexanal 
• 67-56-1 methanol 
• 7367-84-2 (Z)-4-decenoic acid ethyl ester 

Downstream Products

• 505-90-8 (Z)-dec-4-enoic acid 

Relevant articles and documents

Bidentate auxiliary-directed alkenyl C-H allylation: Via exo-palladacycles: Synthesis of branched 1,4-dienes

An alkenyl C-H allylation by an exo-palladacycle intermediate is demonstrated, employing unactivated (Z)-Alkenes and allyl carbonates. With the use of an 8-Aminoquinoline (AQ) derived amide as the directing group, the N,N-bidentate-chelation-Assisted C-H activation protocol proceeded under mild and oxidant-free conditions with excellent selectivity. The utility of this approach is demonstrated by the preparative scale, selective conversion of inseparable Z/E alkenes and ready removal of the amide auxiliary to provide the corresponding ester.

Composition of the cloacal gland secretion of tuatara, Sphenodon punctatus

The lipophilic content of the cloacal gland secretion of the tuatara (Sphenodon punctatus) was investigated. GC/EI-MS Analysis of CH2Cl2 extracts of the secretions revealed triacylglycerols as major glandular constituents. Twelve major medium-chain fatty acids were found to be conjugated to glycerol in different combinations, resulting in complex mixtures. These acids were identified by transesterification and subsequent derivatization of natural samples, and their structures were verified by synthesis. The natural glycerides contain predominantly three of the following acids: octanoic (A), (E)- and (Z)-oct-4-enoic (B and C, resp.), (4E,6Z)-octa-4,6-dienoic (tuataric acid;D), (R)-2,6-dimethylheptanoic (E), (R)-2,6-dimethylhept-5-enoic (F), (Z)-dec-4-enoic (G), (4Z,7Z)-deca-4,7-dienoic (H), (R)-3,7-dimethyloct-6-enoic (I), (R)-4,8-dimethylnon-7-enoic (J), (2R,6S)-2,6,10-trimethylundec-9-enoic (K), and (2R,5E)-2,6,10-trimethylundeca-5,9-dienoic acids (L). Several additional acids, occurring in trace amounts only, were tentatively identified by MS. The elucidation of the absolute configuration of the acids was performed by GC on chiral phases. Individual tuatara show specific mixtures of glycerides with up to 100 components. The individual mixtures may permit individual recognition because the bouquets seem to be stable over years.