736991-21-2 Usage
Description
2-(Morpholinomethyl)benzaldehyde is a benzaldehyde derivative with the chemical formula C10H11NO2. It features a morpholinomethyl group, which is a six-membered heterocyclic amine ring, attached to the benzene ring. 2-(MORPHOLINOMETHYL)BENZALDEHYDE is widely used as a building block or intermediate in organic synthesis and pharmaceutical research due to its unique reactivity and potential applications in the production of pharmaceuticals, agrochemicals, and other fine chemicals.
Uses
Used in Pharmaceutical Industry:
2-(Morpholinomethyl)benzaldehyde is used as a key intermediate for the synthesis of various bioactive molecules. Its morpholinomethyl group provides unique reactivity, enabling the development of new pharmaceutical compounds with potential therapeutic applications.
Used in Agrochemical Industry:
2-(MORPHOLINOMETHYL)BENZALDEHYDE is also utilized as an intermediate in the production of agrochemicals, contributing to the development of innovative and effective products for agricultural use.
Used in Fine Chemicals Production:
2-(Morpholinomethyl)benzaldehyde serves as a building block in the synthesis of various fine chemicals, which are high-purity, specialty chemicals used in a wide range of applications, including fragrances, dyes, and other industrial processes.
Used in Coordination Chemistry:
As a ligand, 2-(Morpholinomethyl)benzaldehyde can form complexes with metal ions, making it a valuable component in coordination chemistry for the development of new materials and catalysts with specific properties and applications.
Check Digit Verification of cas no
The CAS Registry Mumber 736991-21-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 7,3,6,9,9 and 1 respectively; the second part has 2 digits, 2 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 736991-21:
(8*7)+(7*3)+(6*6)+(5*9)+(4*9)+(3*1)+(2*2)+(1*1)=202
202 % 10 = 2
So 736991-21-2 is a valid CAS Registry Number.
InChI:InChI=1/C12H15NO2/c14-10-12-4-2-1-3-11(12)9-13-5-7-15-8-6-13/h1-4,10H,5-9H2
736991-21-2Relevant articles and documents
Catalyst-free photodecarbonylation ofortho-amino benzaldehyde
Li, Lamei,Wang, Songping,Wei, Wentao,Yan, Ming,Zhou, Jingwei
supporting information, p. 3421 - 3426 (2020/06/25)
It is almost a consensus that decarbonylation of the aldehyde group (-CHO) needs to not only be mediated by transition metal catalysts, but also requires severe reaction conditions (high temperature and long reaction time). In this work, inspired by the “conformational-selectivity-based” design strategy, we broke this consensus and discovered a catalyst-free photodecarbonylation of the aldehyde group. It revealed that decarbonylation can be easily achieved with visible light irradiation by introducing a tertiary amine into theortho-position of the aldehyde group. A diverse array of tertiary amines is tolerated by our photodecarbonylation under mild conditions. Furthermore, the (QM) computations of the mechanism and the experiments on well-designed special substrates revealed that our photodecarbonylation depends on the conformational specificity of the aldehyde group and tertiary amine, and occurs through an unusual [1,4]-H shift and a subsequent [1,3]-H shift.
