73712-49-9Relevant academic research and scientific papers
Multiple Extrusion Methods for the Preparation of Sterically Hindered Olefins. An Approach to Tetra-tert-butylethylene
Guziec, Frank S.,Murphy, Christopher J.
, p. 2890 - 2893 (1980)
While twofold extrusion procedures have proved to be very useful in the preparation of very sterically hindered olefins, the extremely hindered tetra-tert-butylethylene (1) has remained elusive.An approach to 1 based on "tied-back" intermediates such as t
Sterically Hindered Alkenes, IV. Preparation of Some Octamethylcycloalkylidenecycloalkanes and Related Compounds
Krebs, Adolf,Rueger, Wolfgang,Ziegenhagen, Birgit,Hebold, Maren,Hardtke, Ingrid,et al.
, p. 277 - 309 (2007/10/02)
Sixteen "tied back" derivatives of tetra-tert-butylethene of type 4 were prepared via the thiadiazoline and selenadiazoline routes, resp.Strain in 4 increases with increasing number of ring members.The compounds 4m, n, p and q represent the alkenes of hig
