7374-90-5

Basic information

• Product Name: 3,4-Dihydro-1,4-methanonaphthalen-2(1H)-one
• Synonyms: 2-Benzonorbornenone;3,4-Dihydro-1,4-methanonaphthalen-2(1H)-one
• CAS NO: 7374-90-5
• Molecular Formula: C₁₁H₁₀O
• Molecular Weight: 158.2
• Mol File: 7374-90-5.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3,4-Dihydro-1,4-methanonaphthalen-2(1H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4-Dihydro-1,4-methanonaphthalen-2(1H)-one(7374-90-5)
• EPA Substance Registry System: 3,4-Dihydro-1,4-methanonaphthalen-2(1H)-one(7374-90-5)

Safety Data

• Hazardous Substances Data: 7374-90-5(Hazardous Substances Data)

Upstream product

• 138751-00-5 tricyclo[6.2.1.0^2,7]undeca-2,4,6-trien-9-ol 
• 4453-90-1 1,4-dihydro-1,4-methanonaphthalene 
• 90364-56-0 (+/-)-exo-2-benzonorbornenyl acetate 
• 4453-90-1 1,4-dihydro-1,4-methanonaphthalene 
• 13153-47-4 (+/-)-exo-2-benzonorbornenol 
• 13153-47-4 (1S,4S)-1,2,3,4-Tetrahydro-1,4-methano-naphthalen-2-ol 
• 583-53-9 2,3-dibromobenzene 
• 118-92-3 anthranilic acid 
• 542-92-7 cyclopenta-1,3-diene 

Downstream Products

• 58742-05-5 endo-N-Methyl-2-aminobenzonorbornene 
• 58742-04-4 endo-2-amino-1,2,3,4-tetrahydro-1,4-methanonaphthalene 
• 2294-87-3 3-(2-propenyl)indene 
• 115919-88-5 1-methyl-5-<3-(endo-benzobicyclo<2.2.1>hept-2-yloxy)-4-methoxyphenyl>-2-imidazolidinone 
• 115897-65-9 {4-Methoxy-3-[(1S,2S,4S)-(1,2,3,4-tetrahydro-1,4-methano-naphthalen-2-yl)oxy]-phenyl}-methylamino-acetonitrile 
• 115897-67-1 1-{4-Methoxy-3-[(1S,2S,4S)-(1,2,3,4-tetrahydro-1,4-methano-naphthalen-2-yl)oxy]-phenyl}-N¹-methyl-ethane-1,2-diamine 
• 131408-21-4 4-Methoxy-3-[(1S,2S,4S)-(1,2,3,4-tetrahydro-1,4-methano-naphthalen-2-yl)oxy]-benzaldehyde 
• 115919-90-9 (1S,2S,4S)-2-(5-Bromo-2-methoxy-phenoxy)-1,2,3,4-tetrahydro-1,4-methano-naphthalene 
• 115898-54-9 4-Bromo-2-[(1S,2S,4S)-(1,2,3,4-tetrahydro-1,4-methano-naphthalen-2-yl)oxy]-phenol 
• 115898-51-6 2-[(1S,2S,4S)-(1,2,3,4-Tetrahydro-1,4-methano-naphthalen-2-yl)oxy]-phenol 
• 93052-30-3 2-benzylamino-2-carboxamido-1,2,3,4-tetrahydro-1,4-methanonaphthalene 

Relevant articles and documents

Highly flexible synthesis of indenylethylamines as ligand precursors for titanium complexes

Various indenylethylamines are synthesized for the first time by reductive amination of 2-(1H-inden-1-yl)acetaldehyde with commercially available primary amines. In addition, a new two-step synthesis of 2-(1 H-inden-1-yl)acetaldehyde that uses inexpensive indene and 2-bromo-1,1-diethoxyethane as starting materials is presented. Finally, a selected indenylethylamine is used as a ligand precursor for the synthesis of a corresponding indenylethylamido titanium complex. The latter result paves the way for applications of corresponding complexes as catalysts for important chemical reactions.

An examination of β-enolization in benzobicyclo[2.2.2], [3.2.1], and [3.2.2] ketones

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EVIDENCE FOR ANTI-BOND MIGRATION IN THE PHOTOREARRANGEMENT OF 2-D-EXOBENZONORBORNENYL-2-CHLORIDE

Photolysis of the title compund to exo-2-benzonorbornenyl methyl ether proceeds with scrambling of the deuterium between C1 and C2, indicative of migration of the anti aryl group.