7376-25-2Relevant articles and documents
Iron-catalyzed direct alkenylation of 2-substituted azaarenes with N -sulfonyl aldimines via C-H bond activation
Qian, Bo,Xie, Pan,Xie, Yinjun,Huang, Hanmin
supporting information; experimental part, p. 2580 - 2583 (2011/06/25)
A novel iron-catalyzed alkenylation of 2-substituted azaarenes through sp3 C-H bond activation has been developed. A favorable E2-elimination is proposed as a key step to cleavage of C-H and C-N bonds for the construction of a C=C bond in high stereoselectivity. This transformation represents an efficient way to synthesize 2-alkenylated azaarenes from simple starting materials.
