73765-25-0Relevant academic research and scientific papers
Photocycloaddition of biscyclopropyl alkenes to C60: An unprecedented approach toward cis-1 tricyclic-fused fullerenes
Tzirakis, Manolis D.,Alberti, Mariza N.,Orfanopoulos, Michael
, p. 3364 - 3367 (2011/09/12)
A novel, simple, and entirely regioselective tandem cycloaddition of biscyclopropyl-substituted alkenes to [60]fullerene has been revealed. This reaction affords cis-1 tricyclic-fused organofullerenes bearing the hitherto elusive 5-4-5 fused tricyclic ring system.
Diastereoselective synthesis of vinylcyclopropanes from dienes and sulfur ylides
Robiette, Rapha?l,Marchand-Brynaert, Jacqueline
, p. 517 - 520 (2008/12/22)
The reaction of aryl- and vinyl-stabilized sulfonium ylides with electron-poor dienes has been investigated. Clean cyclopropanation to 2-aryl- and 2-vinyl-substituted vinylcyclopropanes, with high regio- and stereocontrol, was observed. This new diastereo
