73766-46-8

Upstream product

• 503565-88-6 (1R)-(4-methylphenylsulfinyl)-3-buten-2-one 
• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 107-02-8 acrolein 

Downstream Products

• 73766-37-7 (R)-p-Tolyl-<2-(trimethylsilyloxy)-3-butenyl>-sulfoxid 
• 1033441-65-4 C₁₇H₂₈O₂SSi 
• 73766-34-4 (+)-(R)-(2-Acetoxy-3-butenyl)-p-tolyl-sulfoxid 
• 252032-39-6 1-bromo-(4S)-(4-methylphenylsulfinyl)-(2S,3S)-butane-2,3-diol 
• 503565-87-5 (2S,3S)-1-Bromo-4-((S)-toluene-4-sulfinyl)-butane-2,3-diol 
• 73766-31-1 (+)-(R)-(E-2-Octenyl)-p-tolyl-sulfoxid 
• 73766-36-6 (E)-(+)-(R)-1-(p-tolylsulfinyl)-1,3-butadiene 

Relevant academic research and scientific papers

The sulfinyl moiety as an intramolecular nucleophile. Part 3: Synthesis of (-)-muricatacin

A short, efficient and highly stereoselective synthesis of (-)-(R,R)-muricatacin is reported. The key steps include a highly diastereoselective reduction of a β-ketosulfoxide to a β-hydroxy sulfoxide, regio- and stereoselective bromohydration of an olefin

Stereoselective Synthesis of Alcohols, II Stereochemistry of the Sigmatropic Rearrangement of 3-Substituted 2-Alkenyl Sulfoxides

Rearrangement of the 3-E-substituted allyl sulfoxides 5 to the allyl alcohols 19 and 30 proceeds with low enantiomeric selectivity.In contrast, the 3-Z-substituted allyl sulfoxide 7b rearranged uniformly via the endo-transition state 26.