737699-35-3Relevant academic research and scientific papers
Mechanism of thermal deazetization of 2,3-diazabicyclo[2.2.1]hept-2-ene and its reaction dynamics in supercritical fluids
Reyes, Mayra B.,Carpenter, Barry K.
, p. 10163 - 10176 (2007/10/03)
The mechanism of thermal deazetization of 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) is examined both theoretically and experimentally in this paper. The theoretical work involves CASPT2 ab initio MO calculations using the 6-31G(d) basis set. These calculati
A New and Convenient Synthetic Method for Cyclopropyl Phenyl Sulfides
Tanaka, Kazuhiko,Uneme, Hideki,Matsui, Shuichi,Kaji, Aritsune
, p. 2965 - 2972 (2007/10/02)
The reactions of a variety of 1,3-bis(phenylthio)propanes with butyllithium have been shown to produce cyclopropyl phenyl sulfides in good to high yields.A new and convenient in situ preparation of 1-lithiocyclopropyl phenyl sulfide can be readily carried out by treating 1,3-bis(phenylthio)propane with 2 equiv. of butyllithium at 0 degC in THF.The reaction with electrophiles proceeds in good yield.O-Aryl and O-alkyl S-cyclopropyl dithiocarbonates also can be prepared in good yields. 1,2-Bis(phenylthio)ethane was converted to phenyl vinyl sulfide on treatment with butyllithium, while 1,4-bis(phenylthio)butane was recovered unchanged by a similar treatment.
