73804-18-9

Upstream product

• 85719-38-6 methyl 2-epipedate 
• 73787-22-1 (R)-2-((S)-2,3-Dimethoxy-propyl)-6-hydroxymethyl-3,3-dimethyl-tetrahydro-pyran-4-ol 
• 85708-43-6 (6R,8S)-8,9-Dimethoxy-5,5-dimethyl-non-1-ene-4,6-diol 
• 73787-13-0 2-((4R,5R)-4,5-Dimethyl-[1,3]dioxolan-2-yl)-2-methyl-hex-5-en-3-one 
• 85708-46-9 (4R,6R)-6-((S)-2,3-Dimethoxy-propyl)-4-hydroxy-5,5-dimethyl-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 85708-45-8 (R)-6-((S)-2,3-Dimethoxy-propyl)-5,5-dimethyl-4-oxo-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 85708-42-5 (6R,8S)-6-Benzyloxy-8,9-dimethoxy-5,5-dimethyl-non-1-en-4-ol 
• 85708-41-4 (4R,5R)-2-((2R,4S)-2-Benzyloxy-4,5-dimethoxy-1,1-dimethyl-pentyl)-4,5-dimethyl-[1,3]dioxolane 
• 73787-18-5 (R)-4-Benzyloxy-5-((4R,5R)-4,5-dimethyl-[1,3]dioxolan-2-yl)-1-methoxy-5-methyl-hexan-2-one 
• 92927-36-1 2-((4R,5R)-4,5-Dimethyl-[1,3]dioxolan-2-yl)-2-methyl-propan-1-ol 
• 73787-10-7 (4R,5R)-4,5-dimethyl-2-(1,1-dimethyl-2-oxoethyl)-1,3-dioxolane 
• 85708-39-0 (4R,5R)-2-((R)-2-Benzyloxy-1,1-dimethyl-3-oxiranyl-propyl)-4,5-dimethyl-[1,3]dioxolane 
• 92927-29-2 (R)-6-((S)-2,3-Dimethoxy-propyl)-5,5-dimethyl-4-oxo-tetrahydro-pyran-2-carboxylic acid 
• 73787-19-6 (3R,5S)-3-benzyloxy-5,6-dimethoxy-2,2-dimethyl-hexanal 

Downstream Products

• 73787-23-2 (+)-benzoylpedamide 
• 85708-35-6 (2S,4R,6R)-4-Benzoyloxy-6-((S)-2,3-dimethoxy-propyl)-5,5-dimethyl-tetrahydro-pyran-2-carboxylic acid 
• 85708-36-7 Benzoic acid (2R,4R,6S)-6-chlorocarbonyl-2-((S)-2,3-dimethoxy-propyl)-3,3-dimethyl-tetrahydro-pyran-4-yl ester 

Relevant academic research and scientific papers

REMOTE ACYCLIC STEREOCONTROL; CHIRAL SYNTHESIS OF (+)-PEDAMIDE

Synthesis of optically active pedamide (3), one of the tetrahydropyran moieties of the potent insect poison pederine (1), has been accomplished through a new, remote controlled asymmetric reduction of a ketone as key step.