85708-41-4

Basic information

• Product Name: (4R,5R)-2-((2R,4S)-2-Benzyloxy-4,5-dimethoxy-1,1-dimethyl-pentyl)-4,5-dimethyl-[1,3]dioxolane
• Synonyms: (4R,5R)-2-((2R,4S)-2-Benzyloxy-4,5-dimethoxy-1,1-dimethyl-pentyl)-4,5-dimethyl-[1,3]dioxolane
• CAS NO: 85708-41-4
• Molecular Weight: 366.498
• Mol File: 85708-41-4.mol

Chemical Properties

• CAS DataBase Reference: (4R,5R)-2-((2R,4S)-2-Benzyloxy-4,5-dimethoxy-1,1-dimethyl-pentyl)-4,5-dimethyl-[1,3]dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,5R)-2-((2R,4S)-2-Benzyloxy-4,5-dimethoxy-1,1-dimethyl-pentyl)-4,5-dimethyl-[1,3]dioxolane(85708-41-4)
• EPA Substance Registry System: (4R,5R)-2-((2R,4S)-2-Benzyloxy-4,5-dimethoxy-1,1-dimethyl-pentyl)-4,5-dimethyl-[1,3]dioxolane(85708-41-4)

Safety Data

• Hazardous Substances Data: 85708-41-4(Hazardous Substances Data)

Upstream product

• 73787-17-4 (2S,4R)-4-Benzyloxy-5-((4R,5R)-4,5-dimethyl-[1,3]dioxolan-2-yl)-1-methoxy-5-methyl-hexan-2-ol 
• 74-88-4 methyl iodide 
• 73787-11-8 (4R,5R)-4,5-dimethyl-2-(1,1-dimethyl-(2R)-2-hydroxy-4-pentenyl)-1,3-dioxolane 
• 85708-39-0 (4R,5R)-2-((R)-2-Benzyloxy-1,1-dimethyl-3-oxiranyl-propyl)-4,5-dimethyl-[1,3]dioxolane 
• 73787-15-2 (4R,5R)-2-((R)-2-Benzyloxy-1,1-dimethyl-pent-4-enyl)-4,5-dimethyl-[1,3]dioxolane 
• 73787-10-7 (4R,5R)-4,5-dimethyl-2-(1,1-dimethyl-2-oxoethyl)-1,3-dioxolane 
• 92927-36-1 2-((4R,5R)-4,5-Dimethyl-[1,3]dioxolan-2-yl)-2-methyl-propan-1-ol 
• 73787-18-5 (R)-4-Benzyloxy-5-((4R,5R)-4,5-dimethyl-[1,3]dioxolan-2-yl)-1-methoxy-5-methyl-hexan-2-one 
• 73787-13-0 2-((4R,5R)-4,5-Dimethyl-[1,3]dioxolan-2-yl)-2-methyl-hex-5-en-3-one 
• 597-31-9 2,2-dimethyl-3-hydroxypropionaldehyde 

Downstream Products

• 85708-42-5 (6R,8S)-6-Benzyloxy-8,9-dimethoxy-5,5-dimethyl-non-1-en-4-ol 
• 73787-23-2 (+)-benzoylpedamide 
• 85719-38-6 methyl 2-epipedate 
• 73804-18-9 methyl pedate 
• 85708-36-7 Benzoic acid (2R,4R,6S)-6-chlorocarbonyl-2-((S)-2,3-dimethoxy-propyl)-3,3-dimethyl-tetrahydro-pyran-4-yl ester 
• 85708-35-6 (2S,4R,6R)-4-Benzoyloxy-6-((S)-2,3-dimethoxy-propyl)-5,5-dimethyl-tetrahydro-pyran-2-carboxylic acid 
• 73787-19-6 (3R,5S)-3-benzyloxy-5,6-dimethoxy-2,2-dimethyl-hexanal 

Relevant articles and documents

REMOTE ACYCLIC STEREOCONTROL; CHIRAL SYNTHESIS OF (+)-PEDAMIDE

Synthesis of optically active pedamide (3), one of the tetrahydropyran moieties of the potent insect poison pederine (1), has been accomplished through a new, remote controlled asymmetric reduction of a ketone as key step.

TOTAL SYNTHESIS OF (+)-PEDAMIDE. A NEW, REMOTE CONTROLLED ASYMMETRIC INDUCTION

Total synthesis of optically active pedamide 2, one of the tetrahydropyran moieties of the potent insect poison pederine 1, was achieved by employing a new, remote controlled asymmetric reduction of a ketone as key step.