73853-63-1Relevant academic research and scientific papers
Preparation of Alkanesulfenamides by Selective Elimination of t-Butyl Group in S-Alkyl-S-t-butylsulfilimines
Yamamoto, Tamotsu,Kakimoto, Masa-aki,Maejima, Takeshi,Okawara, Makoto
, p. 1249 - 1250 (2007/10/02)
N-Tosylalkanesulfenamides have been prepared via the reaction of alkyl halides with 2-methyl-2-propanethiolate followed by S-imination with chloramine T and the thermolysis.This method comprises the use of selective elimination of t-butyl group in S-alkyl
Selectivity in the Electrophilic Addition of Carbenes and Nitrenes to Aliphatic Sulphides and to 4-t-Butylthian
Appleton, David C.,Bull, David C.,Kenna, James Mc,Kenna, Jean M. Mc,Walley, Andrew R.
, p. 385 - 390 (2007/10/02)
Photogenerated bisalkoxycarbonyl- and diacetyl-carbenes add exclusively equatorially to 4-t-butylthian and exhibit selectivity in competitive additions to mixtures of dimethyl- and di-isopropyl sulphides.By contrast ethoxy-carbonyl- and p-tolylsulphonyl-nitrene give equal proportions of axial and equatorial adducts with the thian, and show no selectivity in competitive reactions with dialkyl sulphides.The results in most or all cases appear to be determined by kinetic control.
