73879-10-4Relevant academic research and scientific papers
A General Synthetic Approach of Spirovetivanes. The Synthesis of (+/-)-Solavetivone, (+/-)-Hinesol, and Related Compounds
Murai, Akio,Sato, Shingo,Masamune, Tadashi
, p. 2276 - 2281 (1984)
The synthetic procedure leading to preparation of representative compounds, (+/-)-solavetivone and (+)-hinesol, of two classes of spirovetivanes, is described.The procedure involves Diels-Alder reaction of 4-substituted 5,6-dihydro-3,5-dimethylanisoles wi
Π-CYCLIZATION: THE SYNTHESIS OF (+/-)-SOLAVETIVONE AND (+/-)-HINESOL
Murai, Akio,Sato, Shingo,Masamune, Tadashi
, p. 1033 - 1036 (2007/10/02)
A general efficient approach leading to the total synthesis of (+/-)-solavetivone, (+/-)-hinesol, and related spirovetivanes, is described.The process involves stereoselective formation of the asymmetric center at C-7 by ?-cyclisation as a key step.
