73881-09-1Relevant articles and documents
Metallo-phosphorylation of alkenes: a highly regioselective reaction of zirconocene-alkene complexes with chlorophosphate
Lai, Chunbo,Xi, Chanjuan,Chen, Weixuan,Hua, Ruimao
, p. 6295 - 6302 (2007/10/03)
Zirconocene-alkene complexes Cp2Zr(CH2{double bond, long}CHR) reacted with chlorophosphate to form zircono-ethylphosphonate with high regioselectivity, which is versatile and could be converted into various functionalized organophosphonates.
Palladium-catalyzed preparation of dialkyl allylphosphonates. A new preparation of diethyl 2-oxoethylphosphonate
Malet,Moreno-Manas,Pleixats
, p. 2219 - 2228 (2007/10/02)
Palladium-catalyzed Michaelis-Arbuzov reaction of allyl acetates with trialkyl phosphites affords dialkyl allylphosphonates. Diethyl 2-oxoethylphosphonate is efficiently prepared by ozonization of diethyl allylphosphonate.