73881-50-2Relevant articles and documents
The reaction of with iron carbonyls. Unusual complexes formed by ligand cleavage reactions
Cullen, William R.,Williams, Mangayarkarasy
, p. 143 - 150 (2007/10/02)
The phosphines and arsine (L; R=C6H5 or C6H11; n= 2, 3, 4) react with iron carbonyls to afford a range of products.Simple substitution yields (L)Fe(CO)4 and L2Fe(CO)3.Loss of chlorine from the ligands, symbolized (L-Cl), gives coupled complexes of formula 4>2 and loss of chlorine and fluorine gives the η3-allyl bridged derivatives (L-Cl-F)Fe2(CO)6.Only substitution products are obtained from the cyclobutenes.