73892-33-8Relevant academic research and scientific papers
Synthesis of stachybotrin C and all of its stereoisomers: Structure revision
Jacolot, Maiwenn,Jean, Mickael,Tumma, Naresh,Bondon, Arnaud,Chandrasekhar, Srivari,Van De Weghe, Pierre
, p. 7169 - 7175 (2013/08/23)
We disclose the first total synthesis of stachybotrin C, a potent neuroprotective natural compound. All of the four stereoisomers have been prepared and fully characterized with the aim to attribute the absolute configuration of the two adjacent stereocenters of the stachybotrin C.
Alkylation of phenol by nerol in the presence of organoaluminum compounds
Chukicheva,Fedorova,Koroleva,Kuchin
, p. 535 - 540 (2013/02/23)
Alkylation of aluminum phenolate by nerol and of phenol by nerol in the presence of the organoaluminum compounds aluminum phenolate and aluminum isopropylate was studied. The reaction products were isolated and characterized. Several features of the proce
Regio- and stereoselective copper-induced isomerization of 2-alkenyl 2-lithiophenyl ethers to 2-(2-alkenyl)phenols
Barluenga, Jose,Sanz, Roberto,Fananas, Francisco J.
, p. 6103 - 6106 (2007/10/03)
N-Allyl-N-(2-lithioallyl)aniline undergoes intramolecular carbometallation via 5-exo addition on treatment with CuCN. 2-Alkenyl 2-bromophenyl ethers rearrange to 2-(2-alkenyl)phenols by bromine-lithium exchange and further transmetallation with CuCN.
