73892-91-8Relevant articles and documents
COMPETING DIRECTIONS IN THE REACTIONS OF COMPOUNDS OF ELECTROPHILIC SULFUR WITH ALKENES
Bodrikov, I. V.,Ganzhenko, T. S.,Sokova, F. M.,Zefirov, N. S.
, p. 217 - 226 (2007/10/02)
The products and the kinetic relationships of the reactions of chlorothiocyanogen, dithiocyanogen, and 2,4-dinitrobenzenesulfenyl halides with allylbenzenes and styrenes in acetic acid were investigated in the presence of lithium perchlorate and without additions.Considerable variation was found in the electrophilicity of the sulfur-containing reagents (the formation of only products from normal addition and/or solvated adducts and the products from skeletal rearrangement).The nature of the reagent has an effect on the degree of the effect of strong electrolytes in the control of the competing reactions.The kinetic relationships governing the reactions were investigated, and an analysis was made of the data from the reactions of sulfenyl halides with styrenes.