73952-55-3Relevant academic research and scientific papers
Regiochemical Control in Intramolecular Photochemical Reactions of 1,5-Hexadien-3-ones and 1-Acyl-1,5-hexadienes
Wolff, Steven,Agosta, William C.
, p. 1292 - 1299 (2007/10/02)
Both 1,5-hexadien-3-ones (7) and 1-acyl-1,5-hexadienes (8) generally undergo intramolecular photochemical cyclization by way of 1,5 (crossed) closure (see 2), as do other derivatives of 1,5-hexadienes (1).Through study of the photochemistry of 14 members
Cyclization of Substituted 5-Hexenyl Radicals as a Model for Photocyclization of 1,5-Hexadien-3-ones
Agosta, William C.,Wolff, Steven
, p. 3139 - 3141 (2007/10/02)
An examination of substituent effects upon the photochemistry of a number of 1,5-hexadien-3-ones reveals a close parallel with those observed in the cyclization of 5-hexenyl radicals and permits for the first time a rationalization for variations in the regiospecificity of the intramolecular cycloaddition reactions of these dienones.
