73977-87-4

Upstream product

• 100-51-6 benzyl alcohol 
• 5401-62-7 1,2-dibromocyclohexane 
• 1165952-91-9 cyclohexa-1,3-diene 
• 32700-48-4 [(cyclohex-2-en-1-yloxy)methyl]benzene 
• 41513-32-0 trans-2-cyclohexene-1,4-diol 
• 100-44-7 benzyl chloride 
• 53762-85-9 (1S,4R)-Cyclohex-2-ene-1,4-diol 

Downstream Products

• 142532-50-1 1,4-di-O-benzyl-c-3-chlorocyclohexane-r-1,t-2,c-4-triol 
• 142532-46-5 1,4-di-O-benzyl-c-3-ethylcyclohexane-r-1,t-2,c-4-triol 
• 142532-49-8 1,4-di-O-benzyl-c-3-cyanocyclohexane-r-1,t-2,c-4-triol 
• 142532-52-3 c-3-(3-iodoprop-1-ynyl)-2-O-(p-tolyl)-cyclohexane-r-1,t-2,c-4-triol 
• 142532-47-6 1,4-di-O-benzyl-c-3-<3-(tert-butyldiphenylsilyloxy)prop-1-ynyl>cyclohexane-r-1,t-2,c-4-triol 
• 142532-51-2 1,4-di-O-benzyl-c-3-<3-(tert-butyldiphenylsilyloxy)2-O-(p-toluolsulfonyl)prop-1-ynyl>cyclohexane-r-1,t-2,c-4-triol 
• 154388-49-5 (3S,6R)-3,6-Bis-benzyloxy-thiepane 
• 142563-24-4 1,4-di-O-benzyl-c-2,c-3-epoxycyclohexane-r-1,c-4-diol 
• 142532-48-7 1,4-di-O-benzyl-t-2,t-3-epoxycyclohexane-r-1,c-4-diol 

Relevant academic research and scientific papers

Synthesis of 2,9,10-Trioxatricyclo3,8>decane Analogues of Resiniferatoxin

Structurally simplified analogues of the daphnane diterpene resiniferatoxin (RTX) 1, possessing the unusual 2,9,10-trioxatricyclo3,8>decane system have been synthesised stereoselectively from cyclohexa-1,3-diene: functionalisation of th

Stereo- and Regioselective Palladium-Catalyzed 1,4-Dialkoxylation of Conjugated Dienes

A mild method for stereo- and regioselective 1,4-dialkoxylation of conjugated dienes was developed.The reaction is catalysed by palladium(II), and p-benzoquinone is used as the oxidant.It was found that the reaction rate depended on the presence of catalytic amounts of a strong acid.The role of the acid is probably 2-fold: (i) to create a cationic (?-allyl)palladium intermediate and (ii) to protonate the oxygen in the coordinated benzoquinone in the (?-allyl)palladium(benzoquinone) intermediate.

A Facile Synthesis of Cyclitols from Cyclohexene

A facile procedure to synthesize cyclitols from cyclohexene was examined. 1-O-Benzylcyclohex-2-enol (1-benzyloxycyclohexene-2) (I) was prepared from cyclohexene by bromination and successive treatment with sodium benzyloxide.Compound I was converted, by using the same procedure, into DL-trans-1,2-di-O-benzylcyclohex-3-enediol (IIIa), DL-trans- and meso-cis-1,4-di-O-benzylcyclohex-2-enediols (IIIb and IIIc).The main product (IIIa) was converted into dihydroconduritols (IXc and Xc) via the corresponding di-O-benzylcyclohexanetetrols.