73977-87-4Relevant articles and documents
Synthesis of 2,9,10-Trioxatricyclo3,8>decane Analogues of Resiniferatoxin
Bloomfield, Graham C.,Ritchie, Timothy J.,Wrigglesworth, Roger
, p. 1229 - 1236 (2007/10/02)
Structurally simplified analogues of the daphnane diterpene resiniferatoxin (RTX) 1, possessing the unusual 2,9,10-trioxatricyclo3,8>decane system have been synthesised stereoselectively from cyclohexa-1,3-diene: functionalisation of th
A Facile Synthesis of Cyclitols from Cyclohexene
Hasegawa, Akira,Kobayshi, Toshiyuki,Kiso, Makoto
, p. 165 - 168 (2007/10/02)
A facile procedure to synthesize cyclitols from cyclohexene was examined. 1-O-Benzylcyclohex-2-enol (1-benzyloxycyclohexene-2) (I) was prepared from cyclohexene by bromination and successive treatment with sodium benzyloxide.Compound I was converted, by using the same procedure, into DL-trans-1,2-di-O-benzylcyclohex-3-enediol (IIIa), DL-trans- and meso-cis-1,4-di-O-benzylcyclohex-2-enediols (IIIb and IIIc).The main product (IIIa) was converted into dihydroconduritols (IXc and Xc) via the corresponding di-O-benzylcyclohexanetetrols.