73992-96-8Relevant articles and documents
Selective 1,2-Aryl-Aminoalkylation of Alkenes Enabled by Metallaphotoredox Catalysis
Chen, Zimin,Hu, Yuanyuan,Li, Weirong,Liao, Zixuan,Xi, Xiaoxiang,Yuan, Weiming,Zheng, Songlin
supporting information, p. 17910 - 17916 (2020/08/21)
A highly chemo- and regioselective intermolecular 1,2-aryl-aminoalkylation of alkenes by photoredox/nickel dual catalysis is described here. This three-component conjunctive cross-coupling is highlighted by its first application of primary alkyl radicals, which were not compatible in previous reports. The readily prepared α-silyl amines could be transferred to α-amino radicals by photo-induced single electron transfer step. The radical addition/cross-coupling cascade reaction proceeds under mild, base-free and redox-neutral conditions with good functional group tolerance, and importantly, provides an efficient and concise method for the synthesis of structurally valuable α-aryl substituted γ-amino acid derivatives motifs.
NITROGEN-CONTAINING ORGANOSILICON COMPOUNDS LXXXIX. SYNTHESIS AND CHROMATOGRAPHIC AND 13C, 15N, AND 29SI NMR-SPECTRAL INVESTIGATIONS OF PIPERAZINYLSILANES
Lukevits, E.,Liepin'sh, E.,Popova, E. P.,Shatts, V. D.,Belikov, V. A.
, p. 317 - 324 (2007/10/02)
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