74006-69-2

Basic information

• Product Name: chloro(η-ethylene)bis(triphenylphosphine)rhodium(I)
• CAS NO: 74006-69-2
• Molecular Weight: 690.994
• Mol File: 74006-69-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: chloro(η-ethylene)bis(triphenylphosphine)rhodium(I)(CAS DataBase Reference)
• NIST Chemistry Reference: chloro(η-ethylene)bis(triphenylphosphine)rhodium(I)(74006-69-2)
• EPA Substance Registry System: chloro(η-ethylene)bis(triphenylphosphine)rhodium(I)(74006-69-2)

Safety Data

• Hazardous Substances Data: 74006-69-2(Hazardous Substances Data)

Upstream product

• 74-85-1 ethene 
• 15318-33-9 chlorocarbonylbis(triphenylphosphine)rhodium(I) 

Downstream Products

• 70765-24-1 RhCl(CH₃CN)(P(C₆H₅)3)2 
• 15318-33-9 chlorocarbonylbis(triphenylphosphine)rhodium(I) 

Relevant articles and documents

Direct reaction of photogenerated diarylcarbenes at square-planar rhodium(I)

A series of carbene complexes RhCl(CR′2)(PR 3)2 (R = Ph, Toi, Me, R′ = Ph and Tol) have been synthesised through direct reaction of photochemically generated free diarylcarbene with RhCl(CO)(PR3)2. This route to carbene complexes demonstrates the reactivity of simple diarylcarbenes towards transition metal complexes. The reactivity of some of these complexes towards H2, C2H4 and Et3SiH has been investigated.