74010-34-7

Usage

Derivative of indene

A polycyclic aromatic hydrocarbon

Contains an ethynyl group

A functional group with a carbon-carbon triple bond

Used in organic synthesis

For the construction of various organic molecules

Building block

For the construction of larger organic molecules

Potential application

In the fields of materials science and pharmaceuticals

Safety and regulatory compliance

Proper handling and storage protocols should be followed

InChI:InChI=1/C11H8/c1-2-9-7-10-5-3-4-6-11(10)8-9/h1,3-7H,8H2

Upstream product

• 10485-09-3 2-bromoindene 

Downstream Products

• 1562381-39-8 4-(2-formylphenyl)-N-methyl-N-(methylsulfonyl)-N'-phenylbut-2-ynimidamide 

Relevant academic research and scientific papers

1,1-Olefin-bridged bis-(2-indenyl) metallocenes of titanium and zirconium

Tetrasubstituted alkenes bearing geminal 2-indenyl substituents-9-[bis(1H- inden-2-yl)methylidene]-9H-fluorene (6), 2,2′-(2,2-diphenylethene-1,1- diyl)-bis(1H-indene) (7), and 2,2′-(2-propylpent-1-ene-1,1-diyl)-bis(1H- indene) (8) have been synthesized and metallated to form a new class of ansa titanium and zirconium metallocene complexes containing a single sp 2-hybridized carbon bridge. The synthesis of the tetramethylated bis-indenyl Zr-analog is described. In addition, the 1,1-bis-indenyl ethylene is prepared and the Zr complex is modified by olefin metathesis. X-ray structure analyses reveal strained η5 sandwich complexes with highly open metal centers. These complexes have proven active in the polymerization of ethylene and its copolymerization with 1-hexene.

Zn(II)- or Ag(I)-catalyzed 1,4-metathesis reactions between 3-en-1-ynamides and nitrosoarenes

Catalyst-dependent metathesis reactions between 3-en-1-ynamides and nitrosoarenes are described. Particularly notable are the unprecedented 1,4-metathesis reactions catalyzed by Ag(I) or Zn(II) to give 2-propynimidamides and benzaldehyde derivatives. With 3-en-1-ynamides bearing a cycloalkenyl group, 1,4-oxoimination products were produced efficiently. We have developed metathesis/alkynation cascades for unsubstituted 2-propynimidamides and benzaldehyde species generated in situ, to manifest 1,4-hydroxyimination reactions of 3-en-1-ynes. Both 1,4-oxoiminations and 1,4-hydroxyiminations increase the molecular complexity of products.