74023-99-7

Upstream product

• 70838-35-6 DL-(1,3/2,4,6)-1,2,3-tri-O-acetyl-4-bromo-6-bromomethyl-1,2,3-cyclohexanetriol 
• 108-24-7 acetic anhydride 

Downstream Products

• 70878-41-0 DL-1,2,3-tri-O-acetyl-(1,3/2,4,6)-6-acetoxymethyl-4-bromo-1,2,3-cyclohexanetriol 
• 102562-09-4 D,L-(1,3,5/2,4)-1-C-acetoxymethyl-2,3,4-tri-O-acetyl-5-bromo-1,2,3,4-cyclohexanetetrol 
• 104748-81-4 D,L-(1,3,5/2,4)-1-C-acetoxy-methyl-1,2,3,4-tetra-O-acetyl-5-bromo-1,2,3,4-cyclohexanetetrol 
• 102576-55-6 DL-(1,3,5/2,4)-5-acetamido-2,3,4-tracetoxy-1-C-acetoxy-methylcyclohexanol 
• 102576-55-6 DL-penta-N,O-acetylvaliolamine 
• 102576-55-6 DL-penta-N,O-acetyl-5-epivaliolamine 
• 102562-09-4 D,L-(1,2,4/3,5)-1-C-acetoxymethyl-2,3,4-tri-O-acetyl-5-bromo-1,2,3,4-cyclohexanetetrol 
• 86157-99-5 D,L-(1,3/2,4)-1-C-acetoxymethyl-2,3,4-tri-O-acetyl-5-cyclohexene-1,2,3,4-tetrol 
• 86157-99-5 DL-2,3,4,7-tetra-O-acetyl-(1,2,4/3)-1-C-hydroxymethyl-5-cyclohexene-1,2,3,4-tetrol 
• 74024-01-4 DL-(1,3/2)-1,2,3-tri-O-acetyl-4-methylene-5-cyclohexene-1,2,3-triol 

Relevant academic research and scientific papers

Synthetic Studies on the Validamycins. 5. Synthesis of DL-Hydroxyvalidamine and DL-Valienamine

A first synthesis of the peracetyl racemate (25) of hydroxyvalidamine (3), one of the degradation products of antibiotic validamycin B (1), is reported.The present result fully confirmed the proposed structure of 3.The sequence of reactions involves stere

Pseudo-sugars. 5. Synthesis of DL-Validatol and DL-Deoxyvalidatol, and Their Epimers

New cyclitols, validatol and deoxyvalidatol, derived by hydrogenolysis of antibiotic validamycin A, were synthesized as the racemates from readily available tri-O-acetyl-(1,3/2,4,6)-4-bromo-6-bromomethyl-1,2,3-cyclohexanetriol.