86157-99-5

Upstream product

• 108-24-7 acetic anhydride 
• 86861-69-0 DL-3,4,7-tri-O-acetyl-(1,2,4/3)-1-C-hydroxymethyl-5-cyclohexene-1,2,3,4-tetrol 
• 74023-99-7 DL-1,2,3-tri-O-acetyl-(1,3/2,4)-4-bromo-6-methylene-1,2,3-cyclohexenetriol 
• 102562-09-4 D,L-(1,3,5/2,4)-1-C-acetoxymethyl-2,3,4-tri-O-acetyl-5-bromo-1,2,3,4-cyclohexanetetrol 
• 102562-08-3 DL-(1,3,5/2,4)-2,3,4-triacetoxy-1,1'-anhydro-5-bromo-1-C-hydroxymethylcyclohexanol 
• 102562-09-4 D,L-(1,2,4/3,5)-1-C-acetoxymethyl-2,3,4-tri-O-acetyl-5-bromo-1,2,3,4-cyclohexanetetrol 
• 74024-01-4 DL-(1,3/2)-1,2,3-tri-O-acetyl-4-methylene-5-cyclohexene-1,2,3-triol 

Downstream Products

• 81692-25-3 DL-(1,2,4/3)-1-C-acetoxy-1,2,3,4-tetra-O-acetyl-5-cyclohexene-1,2,3,4-tetrol 

Relevant academic research and scientific papers

SYNTHESIS OF DL-PENTA-N,O-ACETYLVALIOLAMINE AND RELATED BRANCHED-CHAIN AMINOCYCLITOLS

Valiolamine (1), a branched-chin aminocyclitol α-D-glucosidase inhibitor, has been synthesized as the racemic penta-N,O-acetyl derivatives (10) from DL-(1,3/2,4)-1,2,3-triacetoxy-4-bromo-6-methylenecyclohxane (2).Epoxidation of 2 with m-chloroperbenzoic a

A SYNTHESIS OF DL-PENTA-N,O-ACETYLVALIOLAMINE

Valiolamine, (2S)-(1,2,4,5/3)-5-amino-1-C-hydroxymethyl-1,2,3,4-cyclohexanetetrol, an α-glucosidase inhibitor isolated from Streptomyces hygroscopicus subsp. limoneus, has been synthesized as the racemic penta-N,O-acetyl derivative starting from DL-1,2,3-