74089-99-9Relevant academic research and scientific papers
REACTION DE METATHESE DES OLEFINES INDUITE PHOTOCHIMIQUEMENT EN PRESENCE D'UN COMPLEXE DE METAL DE TRANSITION. VI. EXISTENCE PROBABLE D'UN METALLODICHLOROCARBENE PRIMAIRE
Garnier, F.,Krausz, P.,Rudler, H.
, p. 77 - 83 (1980)
Photochemically induced metathesis of RCH=CHR' olefins with W(CO)6 and CCl4 gives RCH=CCl2 and R'CH=CCl2.W(CO)6 in CCl4 reacts under illumination with cyclic enol ethers to give products resulting from the insertion of metalladichlorocarbene moieties into the carbon-carbon double bond.A mechanism for the formation of these compounds is outlined.
