74104-15-7Relevant academic research and scientific papers
Dichloromethane as an unusual methylene equivalent. A new entry of highly nucleophilic and selective titanium-methylene complexes for ester methylenation
Yan, Tu-Hsin,Chien, Ching-Ting,Tsai, Chia-Chung,Lin, Kuo-Wei,Wu, Yen-Hsien
, p. 4965 - 4967 (2004)
(Chemical Equation Presented) The successful application of CH 2Cl2-Mg-TiCl4-system mediated methylenation of various esters such as tert-butyl ester and 2,5-cyclohexadiene-1-carboxylate highlights the extraordinary reactivity, selectivity, and the nonbasic nature of this new methylene-carbenoid, which serves as a practical reagent applicable to large-scale synthesis.
