74111-16-3

Upstream product

• 2671-07-0 (+/-)-1r,2c,3c,4c,5t-pentaacetoxy-6t-bromo-cyclohexane 
• 2975-92-0 (+/-)-1D-cyclohexane-1,2,4/3-tetrol 
• 108-24-7 acetic anhydride 
• 78776-45-1 cis-2-cyclohexenyl-1,4-diacetate 
• 39597-90-5 anti-3,6,7-trioxatricyclo<3.2.2.0^2,4>non-8-ene 
• 114838-41-4 t-2,c-3-epoxy-c-4-hydroxy-r-1-cyclohexanol 
• 114924-26-4 anti-3,6,7-trioxatricyclo[3.2.2.0^2,4]nonane 
• 114838-43-6 trans-2,3-epoxy-4-hydroxycyclohexan-1-one 
• 114838-41-4 (1S,2R,5R,6R)-7-Oxa-bicyclo[4.1.0]heptane-2,5-diol 
• 114838-43-6 (1RS,5RS,6RS)-5-hydroxy-7-oxabicyclo[4.1.0]heptan-2-one 
• 41513-32-0 trans-2-cyclohexene-1,4-diol 
• 2975-92-0 (1R,4R)-Cyclohexane-1,2,3,4-tetraol 
• 6671-70-1 2,3-dioxabicyclo[2,2,2]oct-5-ene 
• 4381-96-8 (+/-)-tetraacetylconduritol C 

Downstream Products

• 2975-92-0 (+/-)-1L-cyclohexane-1,3/2,4-tetrol 
• 2975-92-0 (+/-)-cyclohexane-1r,2c,3t,4t-tetraol 
• 2975-92-0 (+/-)-1D-cyclohexane-1,2,4/3-tetrol 

Relevant academic research and scientific papers

Facile stereoselective syntheses of four of the six 1, 2, 3, 4-cyclohexanetetrols: Increasing the accessibility of cyclitols for probing the molecular recognition of saccharides

New and stereoselective syntheses of (1,2,3/4)-, (1,2/3,4)-, (1,4/2,3)-, and (1,2,4/3)-cyclohexanetetrols (1,2,3 and 4 respectively) are described. The known syn and anti 1,4-cyclohex-2-enediols 9 and 10 were used as starting materials. Diols 9 and 10 wer

Catalytic One-Pot Osmylation of Cyclohexadienes: Stereochemical and Conformational Studies of the Resulting Polyols

Catalytic double osmylation is described for a series of cyclohexadienes in acetone/H2O in the presence of the co-oxidant N-methylmorpholine N-oxide (NMO).The formation of polyols occurred stereospecifically with cyclohexadienes 3, 7, and 11a, leading thereby to tetrols 5a, and 9a and to allo-inositol (14a), respectively.To the contrary, trans-cyclohexadiene-diol 15a gave a mixture of the stereoisomeric inositols 18a (epi), 19a (neo), and 20a (chiro).High-field NMR let to clearcut conformational analyses of the polyhydroxylated derivatives.

Total Syntheses of (-)-Conduritol B ((-)-1L-Cyclohex-5-ene-1,3/2,4-tetrol) and of (+)-Conduritol F ((+)-1D-Cyclohex-5-ene-1,2,4/3-tetrol). Determination of the Absolute Configuration of (+)-Leucanthemitol

The 'naked sugar' (+)-(1R,2R,4R)-2-endo-cyano-7-oxabicyclohept-5-en-2-exo-yl acetate ((+)-4) was converted (7 steps , 45percent overall) with high stereoselectivity into (-)-(4R,5S,6R)-4,5,6-tris(oxy)cyclohex-2-en-1-one (

A New and Stereospecific Synthesis of Cyclitols: (1,2,4/3)-, (1,2/3,4)-, and (1,3/2,4)-Cyclohexanetetrols

A new and stereospecific synthesis of (1,2,4/3)-, (1,2/3,4)-, and (1,3/2,4)-cyclohexanetetrols 3a, 4a, and 6a is described.Syn and anti epoxy endoperoxides 9 and 10 were synthesized by epoxidation of endoperoxide 8 with m-chloroperbenzoic acid.Catalytic r

A Facile Synthesis of Cyclitols from Cyclohexene

A facile procedure to synthesize cyclitols from cyclohexene was examined. 1-O-Benzylcyclohex-2-enol (1-benzyloxycyclohexene-2) (I) was prepared from cyclohexene by bromination and successive treatment with sodium benzyloxide.Compound I was converted, by using the same procedure, into DL-trans-1,2-di-O-benzylcyclohex-3-enediol (IIIa), DL-trans- and meso-cis-1,4-di-O-benzylcyclohex-2-enediols (IIIb and IIIc).The main product (IIIa) was converted into dihydroconduritols (IXc and Xc) via the corresponding di-O-benzylcyclohexanetetrols.