74145-18-9

Basic information

• Product Name: p-Nitrophenol-N,N,N',N'-tetramethylformamidinium-(p-nitrophenolat)
• Synonyms: p-Nitrophenol-N,N,N',N'-tetramethylformamidinium-(p-nitrophenolat)
• CAS NO: 74145-18-9
• Molecular Weight: 378.385
• Mol File: 74145-18-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: p-Nitrophenol-N,N,N',N'-tetramethylformamidinium-(p-nitrophenolat)(CAS DataBase Reference)
• NIST Chemistry Reference: p-Nitrophenol-N,N,N',N'-tetramethylformamidinium-(p-nitrophenolat)(74145-18-9)
• EPA Substance Registry System: p-Nitrophenol-N,N,N',N'-tetramethylformamidinium-(p-nitrophenolat)(74145-18-9)

Safety Data

• Hazardous Substances Data: 74145-18-9(Hazardous Substances Data)

Upstream product

• 2214-82-6 Bis(dimethylamino)acetonitrile 
• 830-03-5 4-nitrophenol acetate 
• 100-02-7 4-nitro-phenol 

Relevant articles and documents

Orthoamides, XXXIII.-Contributions to the Chemistry of Bis(dialkylamino)acetonitriles

Bis(dialkylamino)acetonitriles 2a-d react with acetyl chloride and antimony pentachloride to give N,N,N',N'-tetraalkylformamidinium hexachloroantimonates 5a-d.Reaction of p-nitrophenol with 2a,b affords N,N,N',N'-tetraalkylformamidinium salts 8a,b, while reaction of aromatic aldehydes 11 with compounds 2 gives aryl(dialkylamino)acetonitriles 12.Phenyl isothiocyanate reacts with the nitriles 2a-c to give 1:1 adducts for which the structure of N,N,N',N'-tetraalkylformamidinium cyano-N-(phenyl)thioformamidates 19 is proposed.N,N,N',N'-Tetraalkylformamidinium p-toluenesulfonates 30a,b have been prepared from nitriles 2a,b and methyl p-toluoenesulfonate (28).Alkylation of 2c with 28 at higher temperatures affords 1,1-dimethylpiperidinium p-toluoenesulfonate (34) and a small amount (1-piperidinyl)malonodinitrile (33).The nitrile 2a reacts with CH acidic compounds such as ethyl cyanoacetate, malonodinitrile and benzyl cyanide to form the enamines 38.