7415-79-4Relevant articles and documents
Tunable Excimer Circularly Polarized Luminescence in Isohexide Derivatives from Renewable Resources
Zullo, Valerio,Iuliano, Anna,Pescitelli, Gennaro,Zinna, Francesco
supporting information, (2022/02/19)
Organic compounds showing circularly polarized luminescence (CPL) are at the forefront of novel applications and technologies. Here we show the synthesis and chiroptical properties of pyrene and perylene derivatives of inexpensive chiral scaffolds: isomannide and isosorbide. Low-intensity ECD spectra were obtained, suggesting the absence of chromophore interaction in the ground state, except in the case of isomannide bis-perylenecarboxylate, whose ECD spectrum showed a positive exciton couplet. All isomannide derivatives, with the only exception of the one containing a pyrenecarboxylate and a perylenecarboxylate, exhibited excimer CPL spectra, whereas isosorbide derivatives did not show any CPL. Isomannide derivatives bearing two pyrenecarboxylate or two pyrenylacetate groups showed positive CPL emission with dissymmetry factors up to 10?2, which depends on the conformational freedom of the appended units. The CPL sign, Stokes shift and order of magnitude of dissymmetry factor were reproduced by excited-state calculations on a representative compound. Interestingly, the mixed derivative containing pyrenic units with different spacing from the isomannide scaffold showed an oppositely signed excimer band with respect to the homo-substituted derivatives.
Photoinduced symmetry-breaking charge separation: The direction of the charge transfer
Markovic, Vesna,Villamaina, Diego,Barabanov, Igor,Lawson Daku, Latevi Max,Vauthey, Eric
supporting information; experimental part, p. 7596 - 7598 (2011/10/01)
Even flow: Photoinduced symmetry-breaking charge separation takes place in a few picoseconds in a 1,3-bis(perylene)propane dyad in polar solvents. Polarized transient absorption measurements show that the direction of the charge flow is random and entirely governed by the fluctuations of the solvent orientation around the dyad. Copyright
Intelligent fluorescent nucleoside in sensing cytosine base: Importance of hydrophobic nature of perylene fluorophore
Bag, Subhendu Sekhar,Saito, Yoshio,Hanawa, Kazuo,Kodate, Satoshi,Suzuka, Isamu,Saito, Isao
, p. 6338 - 6341 (2007/10/03)
Fluorescence response upon hybridization of perylene labeled oligonucleotide probes depends on the microenvironment experienced by the perylene fluorophore. In mismatched duplex (PerU-C), enhanced fluorescence was observed while in matched dupl