741686-91-9

Upstream product

• 40899-71-6 1-benzenesulfonylindole 
• 50444-99-0 (1R,2S,5R)-menthyl-(S)-p-toluenesulfinate 

Downstream Products

• 741686-93-1 1-(E)-cinnamoyl-2-[(S_s)-(p-tolylsulfinyl)]indole 
• 741686-94-2 1-crotonoyl-2-[(S_s)-(p-tolylsulfinyl)]indole 
• 647024-85-9 2-[(4-methylphenyl)sulfanyl]-1H-indole 
• 741686-92-0 2-[(S_s)-(p-tolylsulfinyl)]indole 

Relevant academic research and scientific papers

Synthesis of chiral sulfinyl-substituted 1-indolyl enones and asymmetric conjugate addition by an arylcopper reagent

The asymmetric conjugate addition of arylcopper reagents to chiral 1-[2-(p-tolylsulfinyl)]indolyl and 1-[3-(p-tolylsulfinyl)]indolyl enones was examined. With the 2-sulfinyl-indolyl derivatives, the reaction of the arylcopper reagent gave high diastereoselectivities (81-88% de's) to afford the adducts in excellent yields, although the similar addition reaction of the 3-sulfinyl derivatives afforded poor diastereoselectivities.