74203-21-7Relevant academic research and scientific papers
Syntheses of Organic Iodides via Reaction of Organoboranes with Sodium Iodide
Kabalka, George W.,Gooch, Eugene E.
, p. 2582 - 2584 (1981)
Organic halides are important synthetic intermediates.We recently reported a new method for iodine incorporation utilizing iodine monochloride.We have found that organoboranes react readily with iodide ion in the presence of mild oxidizing agents such as
A Mild and Convenient Procedure for Conversion of Alkenes into Alkyl Iodides via Reaction of Iodine Monochloride with Organoboranes
Kabalka, George W.,Gooch, Eugene E.
, p. 3578 - 3580 (2007/10/02)
Alkenes are rapidly converted to alkyl iodides under mild conditions via a hydroboration-iodination sequence which utilizes iodine monochloride as the iodination agent.The iodination proceeds with inversion of configuration.A series of functionally substituted iodides was synthesized via the new products.
